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    Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study

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    Type
    Article
    Authors
    Bhatt, Prashant
    Guillerm, Vincent cc
    Datta, Shuvo Jit
    Shkurenko, Aleksander cc
    Eddaoudi, Mohamed cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2020-07-09
    Online Publication Date
    2020-07-09
    Print Publication Date
    2020-07
    Embargo End Date
    2021-07-09
    Permanent link to this record
    http://hdl.handle.net/10754/664170
    
    Metadata
    Show full item record
    Abstract
    Chemical separations are of prime industrial importance; however, they consume a large portion of total industrial energy. Credibly, adsorbent-based separation methods offer the prospective to drastically lessen the energy demand of conventional energy-intensive separation processes. Prominently, a special class of porous materials, namely metal-organic frameworks (MOFs), are reasonably positioned to address various demanding separations in an energy-efficient manner. Out of a myriad of possible topologies for the construction of MOFs, face-transitive nets affording a sole type of window, preferably defined by three- or four-membered rings, can be regarded as ideal blueprints for the construction of MOFs for targeted separations. Intricate separations by MOFs based on some of these topologies are discussed, highlighting the effect of appropriate pore aperture and channel size with prerequisite functional groups on their separation performance. MOFs based on face-transitive nets offer great potential as effective fillers for the construction of practical mixed-matrix membranes (MMMs) with improved separation properties over conventional polymeric membranes.
    Citation
    Bhatt, P. M., Guillerm, V., Datta, S. J., Shkurenko, A., & Eddaoudi, M. (2020). Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study. Chem, 6(7), 1613–1633. doi:10.1016/j.chempr.2020.06.018
    Sponsors
    The authors thank King Abdullah University of Science and Technology for funding and support. M.E. proposed the topic of perspective. M.E. P.B, V.G. S.D. and A.S. reviewed the literature and wrote the manuscript.
    Publisher
    Elsevier BV
    Journal
    Chem
    DOI
    10.1016/j.chempr.2020.06.018
    Additional Links
    https://linkinghub.elsevier.com/retrieve/pii/S2451929420302990
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.chempr.2020.06.018
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

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