Fully Inkjet-Printed, Ultrathin and Conformable Organic Photovoltaics as Power Source Based on Cross-Linked PEDOT:PSS Electrodes
Corzo Diaz, Daniel Alejandro
Hidalgo, Tania C.
Rosas Villalva, Diego
Salama, Khaled N.
KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
Division of Biological and Environmental Sciences and EngineeringOrganic Bioelectronics LaboratoryKing Abdullah University of Science and Technology (KAUST) Thuwal 23955 Kingdom of Saudi Arabia
Electrical Engineering Program
KAUST Solar Center (KSC)
King Abdullah University of Science and Technology (KAUST)Division of Physical Science and EngineeringKAUST Solar CenterKAUST Thuwal 23955 Kingdom of Saudi Arabia
Material Science and Engineering
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Online Publication Date2020-06-14
Print Publication Date2020-08
Embargo End Date2021-06-15
Permanent link to this recordhttp://hdl.handle.net/10754/663597
MetadataShow full item record
AbstractUltra-lightweight solar cells have attracted enormous attention due to their ultra-conformability, flexibility, and compatibility with applications including electronic skin or miniaturized electronics for biological applications. With the latest advancements in printing technologies, printing ultrathin electronics is becoming now a reality. This work offers an easy path to fabricate indium tin oxide (ITO)-free ultra-lightweight organic solar cells through inkjet-printing while preserving high efficiencies. A method consisting of the modification of a poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) ink with a methoxysilane-based cross-linker (3-glycidyloxypropyl)trimethoxysilane (GOPS)) is presented to chemically modify the structure of the electrode layer. Combined with plasma and solvent post-treatments, this approach prevents shunts and ensures precise patterning of solar cells. By using poly(3-hexylthiophene) along rhodanine-benzothiadiazole-coupled indacenodithiophene (P3HT:O-IDTBR), the power conversion efficiency (PCE) of the fully printed solar cells is boosted up to 4.73% and fill factors approaching 65%. All inkjet-printed ultrathin solar cells on a 1.7 µm thick biocompatible parylene substrate are fabricated with PCE reaching up to 3.6% and high power-per-weight values of 6.3 W g−1. After encapsulation, the cells retain their performance after being exposed for 6 h to aqueous environments such as water, seawater, or phosphate buffered saline, paving the way for their integration in more complex circuits for biological systems.
CitationBihar, E., Corzo, D., Hidalgo, T. C., Rosas-Villalva, D., Salama, K. N., Inal, S., & Baran, D. (2020). Fully Inkjet-Printed, Ultrathin and Conformable Organic Photovoltaics as Power Source Based on Cross-Linked PEDOT:PSS Electrodes. Advanced Materials Technologies, 2000226. doi:10.1002/admt.202000226
SponsorsE.B. and D.C. contributed equally to this work. E.B. and D.C. thank Xin Song for fruitful discussions for device optimization and Khulud Almasabi for assistance with the mechanical profilometer. The photograph Figure 1b and the TOC photographs were realized by Anastasia Khrenova, Specialist, Scientific Images and Design, at King Abdullah University of Science and Technology (KAUST).
JournalAdvanced Materials Technologies