Alkyl substituted 4-N-oxazadisilinane cations: A new family of Si protic ionic liquids and its application on esterification reactions

Type
Article
Authors
Alhaddad, Maha cc
Chakraborty, Priyanka cc
Hu, Jinsong
Huang, Kuo-Wei cc
KAUST Department
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2020-04-18
Online Publication Date
2020-04-18
Print Publication Date
2020-06
Embargo End Date
20220-4-13
Submitted Date
2019-11-30
Permanent link to this record
http://hdl.handle.net/10754/663462

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Abstract
A series of oxazadisilinane compounds were prepared and used as Brønsted bases to form a series of 21 siloxane protic ionic liquids (Si-PILs) with four different acids. This new family of Si-PILs were well characterized and examined to catalyze esterification reactions.
Citation
Alhaddad, M., Chakraborty, P., Hu, J., & Huang, K.-W. (2020). Alkyl substituted 4-N-oxazadisilinane cations: A new family of Si protic ionic liquids and its application on esterification reactions. Tetrahedron Letters, 61(23), 151941. doi:10.1016/j.tetlet.2020.151941
Sponsors
We acknowledge the generous financial support from King Abdullah University of Science and Technology (KAUST).
Publisher
Elsevier BV
Journal
Tetrahedron Letters
DOI
10.1016/j.tetlet.2020.151941
Additional Links
https://linkinghub.elsevier.com/retrieve/pii/S0040403920303841
Relations
Is Supplemented By:
  • [Dataset]
    Alhaddad, Maha, Chakraborty, Priyanka, Hu, Jinsong, & Huang, Kuo-Wei. (2020). CCDC 1997809: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC251WGL. DOI: 10.5517/ccdc.csd.cc251wgl Handle: 10754/664906
  • [Dataset]
    Alhaddad, Maha, Chakraborty, Priyanka, Hu, Jinsong, & Huang, Kuo-Wei. (2020). CCDC 1997796: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC251W15. DOI: 10.5517/ccdc.csd.cc251w15 Handle: 10754/664907
  • [Dataset]
    Alhaddad, Maha, Chakraborty, Priyanka, Hu, Jinsong, & Huang, Kuo-Wei. (2020). CCDC 1997794: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC251VZ2. DOI: 10.5517/ccdc.csd.cc251vz2 Handle: 10754/664915
  • [Dataset]
    Alhaddad, Maha, Chakraborty, Priyanka, Hu, Jinsong, & Huang, Kuo-Wei. (2020). CCDC 1997793: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC251VY1. DOI: 10.5517/ccdc.csd.cc251vy1 Handle: 10754/664916
  • [Dataset]
    Alhaddad, Maha, Chakraborty, Priyanka, Hu, Jinsong, & Huang, Kuo-Wei. (2020). CCDC 1997792: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC251VX0. DOI: 10.5517/ccdc.csd.cc251vx0 Handle: 10754/664917
  • [Dataset]
    Alhaddad, Maha, Chakraborty, Priyanka, Hu, Jinsong, & Huang, Kuo-Wei. (2020). CCDC 1997795: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC251W04. DOI: 10.5517/ccdc.csd.cc251w04 Handle: 10754/664928
Collections
Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)