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    Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts.

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    Name:
    Triphenyl_chem.202002150.pdf
    Size:
    1.242Mb
    Format:
    PDF
    Description:
    Accepted manuscript
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    Type
    Article
    Authors
    Liu, Yubing
    Dikhtiarenko, Alla
    Xu, Naizhang
    Sun, Jiawei
    Tang, Jie
    Wang, Kaiqiang
    Xu, Bolian
    Tong, Qing
    Heeres, Hero Jan
    He, Songbo
    Gascon, Jorge cc
    Fan, Yining
    KAUST Department
    Physical Science and Engineering (PSE) Division
    Chemical Engineering Program
    KAUST Catalysis Center (KCC)
    Date
    2020-08-28
    Online Publication Date
    2020-08-28
    Print Publication Date
    2020-09-21
    Embargo End Date
    2021-06-04
    Submitted Date
    2020-05-01
    Permanent link to this record
    http://hdl.handle.net/10754/663252
    
    Metadata
    Show full item record
    Abstract
    The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Here, we present two examples of triphenylphosphine-based COFs (termed as P-COFs) with well-defined crystalline structures, high specific surface areas and good thermal stability. Furthermore, the rhodium catalysts using the obtained P-COFs as support materials show high turnover frequency (TOF) for the hydroformylation of olefins, as well as the excellent recycling performance. This work not only extended phosphine-based COFs family, but also demonstrated their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for heterogeneous catalysis application.
    Citation
    Liu, Y., Dikhtiarenko, A., Xu, N., Sun, J., Tang, J., Wang, K., … Fan, Y. (2020). Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts. Chemistry – A European Journal. doi:10.1002/chem.202002150
    Sponsors
    Y. Liu and Y. Fan thank National Natural Science Foundation of China (NSFC), S. He and H.J. Heeres thank Netherlands Organization for Scientific Research (NWO) for their financial support (NSFC Grant No. 21773107 and NWO-LIFT Programme Grant No.731.016.401) to this work.
    Publisher
    Wiley
    Journal
    Chemistry – A European Journal
    DOI
    10.1002/chem.202002150
    PubMed ID
    32488940
    Additional Links
    https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202002150
    ae974a485f413a2113503eed53cd6c53
    10.1002/chem.202002150
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Engineering Program; KAUST Catalysis Center (KCC)

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