Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts.
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ArticleAuthors
Liu, YubingDikhtiarenko, Alla
Xu, Naizhang
Sun, Jiawei
Tang, Jie
Wang, Kaiqiang
Xu, Bolian
Tong, Qing
Heeres, Hero Jan
He, Songbo
Gascon, Jorge

Fan, Yining
KAUST Department
Physical Science and Engineering (PSE) DivisionChemical Engineering Program
KAUST Catalysis Center (KCC)
Date
2020-08-28Online Publication Date
2020-08-28Print Publication Date
2020-09-21Embargo End Date
2021-06-04Submitted Date
2020-05-01Permanent link to this record
http://hdl.handle.net/10754/663252
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Show full item recordAbstract
The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Here, we present two examples of triphenylphosphine-based COFs (termed as P-COFs) with well-defined crystalline structures, high specific surface areas and good thermal stability. Furthermore, the rhodium catalysts using the obtained P-COFs as support materials show high turnover frequency (TOF) for the hydroformylation of olefins, as well as the excellent recycling performance. This work not only extended phosphine-based COFs family, but also demonstrated their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for heterogeneous catalysis application.Citation
Liu, Y., Dikhtiarenko, A., Xu, N., Sun, J., Tang, J., Wang, K., … Fan, Y. (2020). Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts. Chemistry – A European Journal. doi:10.1002/chem.202002150Sponsors
Y. Liu and Y. Fan thank National Natural Science Foundation of China (NSFC), S. He and H.J. Heeres thank Netherlands Organization for Scientific Research (NWO) for their financial support (NSFC Grant No. 21773107 and NWO-LIFT Programme Grant No.731.016.401) to this work.Publisher
WileyJournal
Chemistry – A European JournalPubMed ID
32488940Additional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202002150ae974a485f413a2113503eed53cd6c53
10.1002/chem.202002150
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