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Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex

dc.contributor.authorZubar, Viktoriia
dc.contributor.authorBorghs, Jannik C.
dc.contributor.authorRueping, Magnus
dc.date.accessioned2020-05-06T09:27:21Z
dc.date.available2020-05-06T09:27:21Z
dc.date.issued2020-05-04
dc.date.submitted2020-04-10
dc.identifier.citationZubar, V., Borghs, J. C., & Rueping, M. (2020). Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex. Organic Letters. doi:10.1021/acs.orglett.0c01273
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.doi10.1021/acs.orglett.0c01273
dc.identifier.urihttp://hdl.handle.net/10754/662745
dc.description.abstractA highly chemoselective base-metal catalyzed hydrogenation and acceptorless dehydrogenation of N-heterocycles is presented. A well-defined Mn complex operates at low catalyst loading (as low as 2 mol %) and under mild reaction conditions. The described catalytic system tolerates various functional groups, and the corresponding reduced heterocycles can be obtained in high yields. Experimental studies indicate a metal-ligand cooperative catalysis mechanism
dc.description.sponsorshipThis work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (FCC/1/1974).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acs.orglett.0c01273
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.orglett.0c01273.
dc.titleHydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganic Letters
dc.rights.embargodate2021-05-04
dc.eprint.versionPost-print
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
kaust.personZubar, Viktoriia
kaust.personRueping, Magnus
refterms.dateFOA2020-05-06T09:56:30Z
kaust.acknowledged.supportUnitOffice of Sponsored Research
dc.date.published-online2020-05-04
dc.date.published-print2020-05-15


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