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dc.contributor.authorCadiau, Amandine
dc.contributor.authorKolobov, Nikita
dc.contributor.authorSrinivasan, Sivaranjani
dc.contributor.authorGoesten, Maarten Gerard
dc.contributor.authorHaspel, Henrik
dc.contributor.authorBavykina, Anastasiya
dc.contributor.authorTchalala, Mohamed
dc.contributor.authorMaity, Partha
dc.contributor.authorGoryachev, Andrey
dc.contributor.authorPoryvaev, Artem
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorFedin, Matvey
dc.contributor.authorMohammed, Omar F.
dc.contributor.authorGascon, Jorge
dc.date.accessioned2020-04-26T09:40:31Z
dc.date.available2020-04-26T09:40:31Z
dc.date.issued2020-05-27
dc.date.submitted2020-01-08
dc.identifier.citationCadiau, A., Kolobov, N., Srinivasan, S., Goesten, M., Haspel, H., Bavykina, A., … Gascon, J. (2020). A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity. Angewandte Chemie International Edition. doi:10.1002/anie.202000158
dc.identifier.issn1433-7851
dc.identifier.pmid32315516
dc.identifier.doi10.1002/anie.202000158
dc.identifier.urihttp://hdl.handle.net/10754/662634
dc.description.abstractWe report the one step synthesis and characterization of a new and robust titanium-based Metal Organic Framework, ACM-1 . In this new structure, based on infinite Ti-O chains and 4,4',4″,4″'-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge separation lifetimes. The suitable energies for band gap and CBM offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
dc.description.sponsorshipWe thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey.V.Fedin thanks the RFBR (18-29-04013).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202000158
dc.rightsArchived with thanks to Angewandte Chemie (International ed. in English)
dc.titleA new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity.
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentKing Abdullah University of Science and Technology, Catalysis Center, SAUDI ARABIA.
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentUltrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
dc.identifier.journalAngewandte Chemie (International ed. in English)
dc.rights.embargodate2021-04-22
dc.eprint.versionPost-print
dc.contributor.institutionNovosibirskij gosudarstvennyj tehniceskij universitet, TOMO, RUSSIAN FEDERATION.
dc.contributor.institutionNovosibirsk State University Faculty of Natural Sciences, TOMO, RUSSIAN FEDERATION.
kaust.personCadiau, Amandine
kaust.personKolobov, Nikita
kaust.personSrinivasan, Sivaranjani
kaust.personGoesten, Maarten Gerard
kaust.personHaspel, Henrik
kaust.personBavykina, Anastasiya
kaust.personTchalala, Mohamed
kaust.personMaity, Partha
kaust.personGoryachev, Andrey
kaust.personEddaoudi, Mohamed
kaust.personMohammed, Omar F.
kaust.personGascon, Jorge
dc.date.accepted2020-04-21
refterms.dateFOA2020-04-26T09:42:16Z
kaust.acknowledged.supportUnitKAUST Office of Sponsored Research
dc.date.published-online2020-05-27
dc.date.published-print2020-08-03


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