A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity.
Goesten, Maarten Gerard
Mohammed, Omar F.
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Engineering Program
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
King Abdullah University of Science and Technology, Catalysis Center, SAUDI ARABIA.
Physical Science and Engineering (PSE) Division
Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
Online Publication Date2020-05-27
Print Publication Date2020-08-03
Embargo End Date2021-04-22
Permanent link to this recordhttp://hdl.handle.net/10754/662634
MetadataShow full item record
AbstractWe report the one step synthesis and characterization of a new and robust titanium-based Metal Organic Framework, ACM-1 . In this new structure, based on infinite Ti-O chains and 4,4',4″,4″'-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge separation lifetimes. The suitable energies for band gap and CBM offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
CitationCadiau, A., Kolobov, N., Srinivasan, S., Goesten, M., Haspel, H., Bavykina, A., … Gascon, J. (2020). A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity. Angewandte Chemie International Edition. doi:10.1002/anie.202000158
SponsorsWe thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey.V.Fedin thanks the RFBR (18-29-04013).
CollectionsArticles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)
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