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    A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity.

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    Name:
    A new titanium.202000158.pdf
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    1.167Mb
    Format:
    PDF
    Description:
    Accepted manuscript
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    Type
    Article
    Authors
    Cadiau, Amandine cc
    Kolobov, Nikita
    Srinivasan, Sivaranjani
    Goesten, Maarten Gerard
    Haspel, Henrik
    Bavykina, Anastasiya
    Tchalala, Mohamed
    Maity, Partha
    Goryachev, Andrey
    Poryvaev, Artem
    Eddaoudi, Mohamed cc
    Fedin, Matvey
    Mohammed, Omar F. cc
    Gascon, Jorge cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Engineering Program
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    KAUST Catalysis Center (KCC)
    KAUST Solar Center (KSC)
    King Abdullah University of Science and Technology, Catalysis Center, SAUDI ARABIA.
    Physical Science and Engineering (PSE) Division
    Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
    Date
    2020-05-27
    Online Publication Date
    2020-05-27
    Print Publication Date
    2020-08-03
    Embargo End Date
    2021-04-22
    Submitted Date
    2020-01-08
    Permanent link to this record
    http://hdl.handle.net/10754/662634
    
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    Abstract
    We report the one step synthesis and characterization of a new and robust titanium-based Metal Organic Framework, ACM-1 . In this new structure, based on infinite Ti-O chains and 4,4',4″,4″'-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge separation lifetimes. The suitable energies for band gap and CBM offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
    Citation
    Cadiau, A., Kolobov, N., Srinivasan, S., Goesten, M., Haspel, H., Bavykina, A., … Gascon, J. (2020). A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity. Angewandte Chemie International Edition. doi:10.1002/anie.202000158
    Sponsors
    We thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey.V.Fedin thanks the RFBR (18-29-04013).
    Publisher
    Wiley
    Journal
    Angewandte Chemie
    DOI
    10.1002/anie.202000158
    PubMed ID
    32315516
    Additional Links
    https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202000158
    ae974a485f413a2113503eed53cd6c53
    10.1002/anie.202000158
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)

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