A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity.
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A new titanium.202000158.pdf
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2021-04-22
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ArticleAuthors
Cadiau, Amandine
Kolobov, Nikita
Srinivasan, Sivaranjani
Goesten, Maarten Gerard
Haspel, Henrik
Bavykina, Anastasiya
Tchalala, Mohamed
Maity, Partha
Goryachev, Andrey
Poryvaev, Artem
Eddaoudi, Mohamed

Fedin, Matvey
Mohammed, Omar F.

Gascon, Jorge

KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Engineering Program
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
King Abdullah University of Science and Technology, Catalysis Center, SAUDI ARABIA.
Physical Science and Engineering (PSE) Division
Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
Date
2020-05-27Online Publication Date
2020-05-27Print Publication Date
2020-08-03Embargo End Date
2021-04-22Submitted Date
2020-01-08Permanent link to this record
http://hdl.handle.net/10754/662634
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We report the one step synthesis and characterization of a new and robust titanium-based Metal Organic Framework, ACM-1 . In this new structure, based on infinite Ti-O chains and 4,4',4″,4″'-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge separation lifetimes. The suitable energies for band gap and CBM offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.Citation
Cadiau, A., Kolobov, N., Srinivasan, S., Goesten, M., Haspel, H., Bavykina, A., … Gascon, J. (2020). A new Titanium Metal Organic Framework with visible-light responsive photocatalytic activity. Angewandte Chemie International Edition. doi:10.1002/anie.202000158Sponsors
We thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey.V.Fedin thanks the RFBR (18-29-04013).Publisher
WileyPubMed ID
32315516Additional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202000158ae974a485f413a2113503eed53cd6c53
10.1002/anie.202000158
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Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)Related articles
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