Catalyst-Free Regioselective (3+2)-Cycloadditions of α, β-unsaturated N -arylnitrones with Alkenes to Access Functionalized Isoxazolidines: A DFT Study.

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Type
Article
Authors
Ghosh, Arnab
Mane, Manoj Vasisht cc
Rode, Haridas
Patil, Siddappa
Sridhar, Balasubramanian
Dateer, Ramesh
KAUST Department
KAUST Catalysis Center (KCC)
King abdullah university of science and technology, KAUST catalysis centre, SAUDI ARABIA.
Physical Science and Engineering (PSE) Division
Date
2020-02-24
Online Publication Date
2020-02-24
Print Publication Date
2020-03-16
Submitted Date
2019-12-16
Permanent link to this record
http://hdl.handle.net/10754/661552

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Abstract
The catalyst-free regioselective [3+2]-cycloaddition of α, β-unsaturated N -arylnitrones with alkenes are developed. The series of synthetically important functionalized isoxazolidines are prepared in good to excellent yields by step economic pathway under ligand and transition metal-free condition. The regioselective cycloaddition pathway supported by control experiment and computational study.
Citation
Ghosh, A., Mane, M., Rode, H., Patil, S., Sridhar, B., & Dateer, R. (2020). Catalyst-Free Regioselective (3+2)-Cycloadditions of α, β-unsaturated N -arylnitrones with Alkenes to Access Functionalized Isoxazolidines: A DFT Study. Chemistry – An Asian Journal. doi:10.1002/asia.201901754
Sponsors
he authors thank, DST-SERB, Government of India, for the financial support through the research grant: FileNos. SB/S2/RJN-042/2017 andECR/2017/002207.Author also thanks to Jain University, India, for financial support.
Publisher
Wiley
Journal
Chemistry, an Asian journal
DOI
10.1002/asia.201901754
Additional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/asia.201901754
Collections
Articles; Physical Science and Engineering (PSE) Division; KAUST Catalysis Center (KCC)