Catalyst-Free Regioselective (3+2)-Cycloadditions of α, β-unsaturated N -arylnitrones with Alkenes to Access Functionalized Isoxazolidines: A DFT Study.
Mane, Manoj Vasisht
KAUST DepartmentKAUST Catalysis Center (KCC)
King abdullah university of science and technology, KAUST catalysis centre, SAUDI ARABIA.
Physical Science and Engineering (PSE) Division
Online Publication Date2020-02-24
Print Publication Date2020-03-16
Permanent link to this recordhttp://hdl.handle.net/10754/661552
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AbstractThe catalyst-free regioselective [3+2]-cycloaddition of α, β-unsaturated N -arylnitrones with alkenes are developed. The series of synthetically important functionalized isoxazolidines are prepared in good to excellent yields by step economic pathway under ligand and transition metal-free condition. The regioselective cycloaddition pathway supported by control experiment and computational study.
CitationGhosh, A., Mane, M., Rode, H., Patil, S., Sridhar, B., & Dateer, R. (2020). Catalyst-Free Regioselective (3+2)-Cycloadditions of α, β-unsaturated N -arylnitrones with Alkenes to Access Functionalized Isoxazolidines: A DFT Study. Chemistry – An Asian Journal. doi:10.1002/asia.201901754
Sponsorshe authors thank, DST-SERB, Government of India, for the financial support through the research grant: FileNos. SB/S2/RJN-042/2017 andECR/2017/002207.Author also thanks to Jain University, India, for financial support.
JournalChemistry, an Asian journal