An update on Formic Acid Dehydrogenation by Homogeneous Catalysis.
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Type
ArticleKAUST Department
Chemical Science ProgramHomogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
King Abdullah University of Science and Technology, Chemical Sciences, 4700 KAUST, 23955-6900, Thuwal, SAUDI ARABIA.
Physical Science and Engineering (PSE) Division
Date
2020-02-07Online Publication Date
2020-02-07Print Publication Date
2020-04Submitted Date
2019-12-04Permanent link to this record
http://hdl.handle.net/10754/661498
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Formic acid (FA) has been extensively studied as one of the most promising hydrogen energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of CO 2 and H 2 that can be applied in fuel cells. A large number of transition-metal based homogeneous catalysts with high activity and selectivity have been reported for the selective FA dehydrogentaion. In this review, we discussed the recent development of C,N/N,N-ligand and pincer ligand-based homogeneous catalysts for the FA dehydrogenation reaction. Some representative catalysts are further evaluated by the CON/COF assessment (catalyst on-cost number)/(catalyst on-cost frequency).Conclusive remarks are provided with the future challenges and opportunities.Citation
Guan, C., Pan, Y., Zhang, T., Ajitha, M. J., & Huang, K.-W. (2020). An update on Formic Acid Dehydrogenation by Homogeneous Catalysis. Chemistry – An Asian Journal. doi:10.1002/asia.201901676Sponsors
This work was supported by King Abdullah University of Science and Technology (KAUST).Publisher
WileyJournal
Chemistry – An Asian JournalAdditional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/asia.201901676ae974a485f413a2113503eed53cd6c53
10.1002/asia.201901676