Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

Citation

Cadiau, A., Xie, L. S., Kolobov, N., Shkurenko, A., Qureshi, M., Tchalala, M. R., … Gascon, J. (2019). Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties. Chemistry of Materials, 32(1), 97–104. doi:10.1021/acs.chemmater.9b02462

Sponsors

The work at MIT was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (DESC0018235). L.S.X. and S.S.P. thank the National Science Foundation for support through the Graduate Research Fellowship Program (1122374). A.C. thanks the program P.I.A “MOPGA” (APPAT) for funding. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation grant number ACI-1548562, and the PICS machine, Coeus, which is supported by the NSF (DMS1624776). The KAUST Office of Sponsored Research is gratefully acknowledged for funding through the 2019 CRG program.

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. DOI: 10.5517/ccdc.csd.cc223pws HANDLE: 10754/664843

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. DOI: 10.5517/ccdc.csd.cc223r65 HANDLE: 10754/664844

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Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC)