Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties
Xie, Lilia S.
Park, Sarah S.
Hendon, Christopher H.
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Online Publication Date2019-12-18
Print Publication Date2020-01-14
Embargo End Date2020-12-18
Permanent link to this recordhttp://hdl.handle.net/10754/661365
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AbstractNowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.
CitationCadiau, A., Xie, L. S., Kolobov, N., Shkurenko, A., Qureshi, M., Tchalala, M. R., … Gascon, J. (2019). Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties. Chemistry of Materials, 32(1), 97–104. doi:10.1021/acs.chemmater.9b02462
SponsorsThe work at MIT was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (DESC0018235). L.S.X. and S.S.P. thank the National Science Foundation for support through the Graduate Research Fellowship Program (1122374). A.C. thanks the program P.I.A “MOPGA” (APPAT) for funding. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation grant number ACI-1548562, and the PICS machine, Coeus, which is supported by the NSF (DMS1624776). The KAUST Office of Sponsored Research is gratefully acknowledged for funding through the 2019 CRG program.
PublisherAmerican Chemical Society (ACS)
JournalChemistry of Materials
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