Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study.
Type
ArticleAuthors
Mallick, Arijit
Liang, Hanfeng

Shekhah, Osama

Jia, Jiangtao

Mouchaham, Georges

Shkurenko, Aleksander

Belmabkhout, Youssef

Alshareef, Husam N.

Eddaoudi, Mohamed

KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Functional Nanomaterials and Devices Research Group
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
KAUST Grant Number
CRG2017Date
2020Embargo End Date
2021-01-18Permanent link to this record
http://hdl.handle.net/10754/661102
Metadata
Show full item recordAbstract
In this work, a pre-designed Zr-based-MOF encompassing an organic linker with a redox active core is synthesized and its structure-property relationship as a supercapacitor electrode is investigated. An enhanced performance is revealed by the combination of this MOF's high porosity and redox core incorporation, which alters its double-layer and pseudocapacitance, respectively. An increase in the capacitance performance by a factor of two is achieved via post-synthetic structure rigidification using organic pillars.Citation
Mallick, A., Liang, H., Shekhah, O., Jia, J., Mouchaham, G., Shkurenko, A., … Eddaoudi, M. (2020). Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study. Chemical Communications. doi:10.1039/c9cc08860aSponsors
This work was financially supported by the King Abdullah University of Science and Technology (KAUST) under Award No.OSR-CRG2017 3379.Publisher
Royal Society of Chemistry (RSC)Additional Links
http://xlink.rsc.org/?DOI=C9CC08860ARelations
Is Supplemented By:- [Dataset]
Mallick, Arijit, Liang, Hanfeng, Shekhah, Osama, Jia, Jiangtao, Mouchaham, Georges, Shkurenko, Aleksander, Belmabkhout, Youssef, Alshareef, Husam N., & Eddaoudi, Mohamed. (2020). CCDC 1849328: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC202CR7. DOI: 10.5517/ccdc.csd.cc202cr7 Handle: 10754/664839
ae974a485f413a2113503eed53cd6c53
10.1039/c9cc08860a