Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study.
Alshareef, Husam N.
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Functional Nanomaterials and Devices Research Group
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
KAUST Grant NumberCRG2017
Embargo End Date2021-01-18
Permanent link to this recordhttp://hdl.handle.net/10754/661102
MetadataShow full item record
AbstractIn this work, a pre-designed Zr-based-MOF encompassing an organic linker with a redox active core is synthesized and its structure-property relationship as a supercapacitor electrode is investigated. An enhanced performance is revealed by the combination of this MOF's high porosity and redox core incorporation, which alters its double-layer and pseudocapacitance, respectively. An increase in the capacitance performance by a factor of two is achieved via post-synthetic structure rigidification using organic pillars.
CitationMallick, A., Liang, H., Shekhah, O., Jia, J., Mouchaham, G., Shkurenko, A., … Eddaoudi, M. (2020). Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study. Chemical Communications. doi:10.1039/c9cc08860a
SponsorsThis work was financially supported by the King Abdullah University of Science and Technology (KAUST) under Award No.OSR-CRG2017 3379.
PublisherRoyal Society of Chemistry (RSC)
RelationsIs Supplemented By:
Mallick, Arijit, Liang, Hanfeng, Shekhah, Osama, Jia, Jiangtao, Mouchaham, Georges, Shkurenko, Aleksander, Belmabkhout, Youssef, Alshareef, Husam N., & Eddaoudi, Mohamed. (2020). CCDC 1849328: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC202CR7. DOI: 10.5517/ccdc.csd.cc202cr7 Handle: 10754/664839