Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study.
Type
ArticleAuthors
Mallick, Arijit
Liang, Hanfeng
Shekhah, Osama
Jia, Jiangtao
Mouchaham, Georges
Shkurenko, Aleksander
Belmabkhout, Youssef
Alshareef, Husam N.
Eddaoudi, Mohamed
KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Functional Nanomaterials and Devices Research Group
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
KAUST Grant Number
CRG2017Date
2020Permanent link to this record
http://hdl.handle.net/10754/661102Metadata
Show full item recordAbstract
In this work, a pre-designed Zr-based-MOF encompassing an organic linker with a redox active core is synthesized and its structure-property relationship as a supercapacitor electrode is investigated. An enhanced performance is revealed by the combination of this MOF's high porosity and redox core incorporation, which alters its double-layer and pseudocapacitance, respectively. An increase in the capacitance performance by a factor of two is achieved via post-synthetic structure rigidification using organic pillars.Citation
Mallick, A., Liang, H., Shekhah, O., Jia, J., Mouchaham, G., Shkurenko, A., … Eddaoudi, M. (2020). Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study. Chemical Communications. doi:10.1039/c9cc08860aSponsors
This work was financially supported by the King Abdullah University of Science and Technology (KAUST) under Award No.OSR-CRG2017 3379.Publisher
Royal Society of Chemistry (RSC)Additional Links
http://xlink.rsc.org/?DOI=C9CC08860ARelations
Is Supplemented By:- [Dataset]
Mallick, Arijit, Liang, Hanfeng, Shekhah, Osama, Jia, Jiangtao, Mouchaham, Georges, Shkurenko, Aleksander, Belmabkhout, Youssef, Alshareef, Husam N., & Eddaoudi, Mohamed. (2020). CCDC 1849328: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC202CR7. DOI: 10.5517/ccdc.csd.cc202cr7 Handle: 10754/664839