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dc.contributor.authorChen, Zhijie
dc.contributor.authorThiam, Zeynabou
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorWeselinski, Lukasz Jan
dc.contributor.authorAdil, Karim
dc.contributor.authorJiang, Hao
dc.contributor.authorAlezi, Dalal
dc.contributor.authorAssen, Ayalew Hussen Assen
dc.contributor.authorO'Keeffe, Michael
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2020-01-01T12:48:28Z
dc.date.available2020-01-01T12:48:28Z
dc.date.issued2019-12-03
dc.identifier.citationChen, Z., Thiam, Z., Shkurenko, A., Weselinski, L. J., Adil, K., Jiang, H., … Eddaoudi, M. (2019). Enriching the Reticular Chemistry Repertoire with Minimal Edge-Transitive Related Nets: Access to Highly Coordinated Metal–Organic Frameworks Based on Double Six-Membered Rings as Net-Coded Building Units. Journal of the American Chemical Society, 141(51), 20480–20489. doi:10.1021/jacs.9b11260
dc.identifier.doi10.1021/jacs.9b11260
dc.identifier.urihttp://hdl.handle.net/10754/660908
dc.description.abstractMinimal edge-transitive nets are regarded as suitable blueprints for the successful practice of reticular chemistry, and par excellence ideal for the deliberate design and rational construction of highly coordinated metal-organic frameworks (MOFs). We report the systematic generation of the highly connected minimal edge-transitive related nets (transitivity [32]) from parent edge-transitive nets (transitivity [21] or [11]), and their use as a guide for the deliberate design and directional assembly of highly coordinated MOFs from their associated net-coded building units (net-cBUs), 12-connected (12-c) double six-membered ring (d6R) building units. Notably, the generated related nets enclose the distinctive highly coordinated d6R (12-c) due to the subsequent coordination number increase in one node of the resultant new related net; that is, the (3,4,12)-c kce net is the (4,6)-c soc-related net, and the (3,6,12)-c kex and urx nets are the (6,6)-c nia-related nets. Intuitively, the combination of 12-connected hexagonal prismatic rare-earth (RE) nonanuclear [RE9(μ3-O)2(μ3-OH)12(O2C-)12] carboxylate-based clusters with purposely chosen organic or organic-inorganic hybrid building units led to the formation of the targeted highly coordinated MOFs based on selected minimal edge-transitive related nets. Interestingly, the kex-MOFs can alternatively be regarded as a zeolite-like MOF (ZMOF) based on the zeolite underlying topology afx, by considering the dodecacarboxylate ligand as a d6R building unit, delineating a new avenue toward the construction of ZMOFs through the composite building units as net-cBUs. This represents a significant step toward the effective discovery and design of novel minimal edge-transitive and highly coordinated materials using the d6Rs as net-cBUs.
dc.description.sponsorshipResearch reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/abs/10.1021/jacs.9b11260
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/jacs.9b11260.
dc.titleEnriching the Reticular Chemistry Repertoire with Minimal Edge-Transitive Related Nets: Access to Highly Coordinated Metal-Organic Frameworks Based on Double Six-Membered Rings as Net-Coded Building Units.
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.rights.embargodate2020-12-04
dc.eprint.versionPost-print
dc.contributor.institutionSchool of Molecular Sciences , Arizona State University , Tempe , Arizona 85287 , United States.
kaust.personChen, Zhijie
kaust.personThiam, Zeynabou
kaust.personShkurenko, Aleksander
kaust.personWeselinski, Lukasz Jan
kaust.personAdil, Karim
kaust.personJiang, Hao
kaust.personAlezi, Dalal
kaust.personAssen, Ayalew Hussen Assen
kaust.personEddaoudi, Mohamed
refterms.dateFOA2020-12-04T00:00:00Z
dc.date.published-online2019-12-03
dc.date.published-print2019-12-26


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