• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguidePlumX LibguideSubmit an Item

    Statistics

    Display statistics

    Enriching the Reticular Chemistry Repertoire with Minimal Edge-Transitive Related Nets: Access to Highly Coordinated Metal-Organic Frameworks Based on Double Six-Membered Rings as Net-Coded Building Units.

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Thumbnail
    Name:
    ja-2019-11260c.R1_Proof_hi.pdf
    Size:
    1.780Mb
    Format:
    PDF
    Description:
    Accepted manuscript
    Download
    Type
    Article
    Authors
    Chen, Zhijie cc
    Thiam, Zeynabou
    Shkurenko, Aleksander cc
    Weselinski, Lukasz Jan cc
    Adil, Karim cc
    Jiang, Hao cc
    Alezi, Dalal cc
    Assen, Ayalew Hussen Assen
    O'Keeffe, Michael
    Eddaoudi, Mohamed cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2019-12-03
    Online Publication Date
    2019-12-03
    Print Publication Date
    2019-12-26
    Embargo End Date
    2020-12-04
    Permanent link to this record
    http://hdl.handle.net/10754/660908
    
    Metadata
    Show full item record
    Abstract
    Minimal edge-transitive nets are regarded as suitable blueprints for the successful practice of reticular chemistry, and par excellence ideal for the deliberate design and rational construction of highly coordinated metal-organic frameworks (MOFs). We report the systematic generation of the highly connected minimal edge-transitive related nets (transitivity [32]) from parent edge-transitive nets (transitivity [21] or [11]), and their use as a guide for the deliberate design and directional assembly of highly coordinated MOFs from their associated net-coded building units (net-cBUs), 12-connected (12-c) double six-membered ring (d6R) building units. Notably, the generated related nets enclose the distinctive highly coordinated d6R (12-c) due to the subsequent coordination number increase in one node of the resultant new related net; that is, the (3,4,12)-c kce net is the (4,6)-c soc-related net, and the (3,6,12)-c kex and urx nets are the (6,6)-c nia-related nets. Intuitively, the combination of 12-connected hexagonal prismatic rare-earth (RE) nonanuclear [RE9(μ3-O)2(μ3-OH)12(O2C-)12] carboxylate-based clusters with purposely chosen organic or organic-inorganic hybrid building units led to the formation of the targeted highly coordinated MOFs based on selected minimal edge-transitive related nets. Interestingly, the kex-MOFs can alternatively be regarded as a zeolite-like MOF (ZMOF) based on the zeolite underlying topology afx, by considering the dodecacarboxylate ligand as a d6R building unit, delineating a new avenue toward the construction of ZMOFs through the composite building units as net-cBUs. This represents a significant step toward the effective discovery and design of novel minimal edge-transitive and highly coordinated materials using the d6Rs as net-cBUs.
    Citation
    Chen, Z., Thiam, Z., Shkurenko, A., Weselinski, L. J., Adil, K., Jiang, H., … Eddaoudi, M. (2019). Enriching the Reticular Chemistry Repertoire with Minimal Edge-Transitive Related Nets: Access to Highly Coordinated Metal–Organic Frameworks Based on Double Six-Membered Rings as Net-Coded Building Units. Journal of the American Chemical Society, 141(51), 20480–20489. doi:10.1021/jacs.9b11260
    Sponsors
    Research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
    Publisher
    American Chemical Society (ACS)
    Journal
    Journal of the American Chemical Society
    DOI
    10.1021/jacs.9b11260
    Additional Links
    https://pubs.acs.org/doi/abs/10.1021/jacs.9b11260
    ae974a485f413a2113503eed53cd6c53
    10.1021/jacs.9b11260
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

    entitlement

     
    DSpace software copyright © 2002-2021  DuraSpace
    Quick Guide | Contact Us | Send Feedback
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.