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dc.contributor.authorWu, Hao
dc.contributor.authorAlmalki, Maram M.
dc.contributor.authorXu, Xiangming
dc.contributor.authorLei, Yongjiu
dc.contributor.authorMing, Fangwang
dc.contributor.authorMallick, Arijit
dc.contributor.authorRoddatis, Vladimir
dc.contributor.authorLopatin, Sergei
dc.contributor.authorShekhah, Osama
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorAlshareef, Husam N.
dc.date.accessioned2019-12-30T08:23:00Z
dc.date.available2019-12-30T08:23:00Z
dc.date.issued2019-12-11
dc.identifier.citationWu, H., Almalki, M., Xu, X., Lei, Y., Ming, F., Mallick, A., … Alshareef, H. N. (2019). MXene Derived Metal–Organic Frameworks. Journal of the American Chemical Society. doi:10.1021/jacs.9b11446
dc.identifier.doi10.1021/jacs.9b11446
dc.identifier.urihttp://hdl.handle.net/10754/660867
dc.description.abstractSynthesis of nanoscale metal−organic frameworks (MOFs) is a highly challenging task because conventional soluble metal salt precursors are not easy to manipulate spatially, thus normally leading to bulk MOFs. In the present work, V2CTx MXene is demonstrated for the first time as a metal precursor to fabricate twodimensional (2D) MOF nanosheets, whose thickness (6 to 18 nm) can be tuned by varying the reaction temperature. The highly electronegative surface atoms of MXene and sufficient accessible attacking sites for ligands are responsible for the evolution of 2D MOF nanosheets. Moreover, highly oriented and smooth MOF thin films have been grown based on these nanosheets using a convenient spin coating process. With the impregnation of nonvolatile H3PO4, the MOF thin film exhibits a protonconducting property. This study demonstrates that highquality 2D MOF sheets and thin films are enabled by 2D MXene precursors. We believe that the high-quality MOF films prepared in this study pave the way for many device applications.
dc.description.sponsorshipThis work was financially supported by King Abdullah University of Science and Technology (KAUST) under Award No. OSR-CRG2017-3379.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/jacs.9b11446
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.9b11446.
dc.titleMXene Derived Metal–Organic Frameworks
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentElectron Microscopy
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentFunctional Nanomaterials and Devices Research Group
dc.contributor.departmentMaterial Science and Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.rights.embargodate2020-12-11
dc.eprint.versionPost-print
dc.contributor.institutionGerman Research Centre for Geosciences, GFZ, Telegrafenberg, 14473 Potsdam, Germany
kaust.personWu, Hao
kaust.personAlmalki, Maram
kaust.personXu, Xiangming
kaust.personLei, Yongjiu
kaust.personMing, Fangwang
kaust.personMallick, Arijit
kaust.personLopatin, Sergei
kaust.personShekhah, Osama
kaust.personEddaoudi, Mohamed
kaust.personAlshareef, Husam N.
kaust.grant.numberOSR-CRG2017-3379
refterms.dateFOA2019-12-30T11:05:59Z
kaust.acknowledged.supportUnitOSR
dc.date.published-online2019-12-11
dc.date.published-print2019-12-26


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