Cascade Cross-Coupling of Dienes: Photoredox and Nickel Dual Catalysis
KAUST DepartmentKAUST Catalysis Center (KCC)
Chemical Science Program
Physical Sciences and Engineering (PSE) Division
Online Publication Date2019-11-28
Print Publication Date2020-01-02
Permanent link to this recordhttp://hdl.handle.net/10754/660485
MetadataShow full item record
AbstractChemical transformations based on cascade reactions have the potential to simplify the preparation of diverse and architecturally complex molecules dramatically. Herein, we disclose an unprecedented and efficient method for the cross-coupling of radical precursors, dienes, and electrophilic coupling partners via a photoredox- and nickel-enabled cascade cross-coupling process. The cascade reaction furnishes a diverse array of saturated carbo- and heterocyclic scaffolds, thus providing access to a quick gain in C−C bond saturation
CitationHuang, L., Zhu, C., Yi, L., Yue, H., Kancherla, R., & Rueping, M. (2019). Cascade Cross-Coupling of Dienes: Photoredox and Nickel Dual Catalysis. Angewandte Chemie. doi:10.1002/ange.201911109
SponsorsThe research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007–2013)/ERC Grant Agreement no. 617044 (SunCatChem).
Except where otherwise noted, this item's license is described as This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.