Type
ArticleKAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2019-11-08Embargo End Date
2020-11-08Permanent link to this record
http://hdl.handle.net/10754/660228
Metadata
Show full item recordAbstract
An unprecedented nickel-catalyzed decarbonylative silylation via CO extrusion intramolecular recombination fragment coupling of unstrained and nondirecting group-Assisted silyl ketones is described. The inexpensive and readily available catalyst performs under mild reaction conditions and enables the synthesis of structurally diverse arylsilanes, including heterocyclic and natural product derivatives.Citation
Srimontree, W., Lakornwong, W., & Rueping, M. (2019). Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones. Organic Letters. doi:10.1021/acs.orglett.9b03487Sponsors
W.L. was supported by the Thailand Research Fund through the Royal Golden Jubilee Ph.D. Program for the one-year exchange fellowship to RWTH-Aachen University. We thank Tengfei Ji for performing the large scale experiment.Publisher
American Chemical Society (ACS)Journal
Organic LettersAdditional Links
https://pubs.acs.org/doi/10.1021/acs.orglett.9b03487ae974a485f413a2113503eed53cd6c53
10.1021/acs.orglett.9b03487