Carrier Extraction from Perovskite to Polymeric Charge Transport Layers Probed by Ultrafast Transient Absorption Spectroscopy.
Khan, Jafar Iqbal
De Wolf, Stefaan
KAUST DepartmentMaterials Science and Engineering Program
KAUST Solar Center (KSC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
Embargo End Date2020-10-22
Permanent link to this recordhttp://hdl.handle.net/10754/660113
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AbstractThe efficiency of state-of-the-art perovskite solar cells is limited by carrier recombination at defects and interfaces. Thus, understanding these losses and how to reduce them is the way forward toward the Shockley-Queisser limit. Here, we demonstrate that ultrafast transient absorption spectroscopy can directly probe hole extraction and recombination dynamics at perovskite/hole transport layer (HTL) interfaces. To illustrate this, we employed PDPP-3T as HTL because its ground-state absorption is at lower energy than the perovskite's photobleach, enabling direct monitoring of interfacial hole extraction and recombination. Moreover, by fitting the carrier dynamics using a diffusion model, we determined the carrier mobility. Afterwards, by varying the perovskite thickness, we distinguished between carrier diffusion and carrier extraction at the interface. Lastly, we prepared device-like structures, TiO2/perovskite/PDPP-3T stacks, and observed reduced carrier recombination in the perovskite. From PDPP-3T carrier dynamics, we deduced that hole extraction is one order faster than recombination of holes at the interface.
CitationUgur, E., Khan, J. I., Aydin, E., Wang, M., Kirkus, M., Neophytou, M., … Laquai, F. (2019). Carrier Extraction from Perovskite to Polymeric Charge Transport Layers Probed by Ultrafast Transient Absorption Spectroscopy. The Journal of Physical Chemistry Letters, 6921–6928. doi:10.1021/acs.jpclett.9b02502
SponsorsThis publication is based upon work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No: OSR2018-CARF/CCF-3079.
PublisherAmerican Chemical Society (ACS)