Show simple item record

dc.contributor.authorFalconnet, Alban
dc.contributor.authorMagre, Marc
dc.contributor.authorMaity, Bholanath
dc.contributor.authorCavallo, Luigi
dc.contributor.authorRueping, Magnus
dc.date.accessioned2019-11-04T12:35:52Z
dc.date.available2019-11-04T12:35:52Z
dc.date.issued2019-10-23
dc.identifier.citationFalconnet, A., Magre, M., Maity, B., Cavallo, L., & Rueping, M. (2019). Asymmetric Magnesium-Catalyzed Hydroboration by Metal-Ligand Cooperative Catalysis. Angewandte Chemie. doi:10.1002/ange.201908012
dc.identifier.doi10.1002/ange.201908012
dc.identifier.doi10.1002/anie.201908012
dc.identifier.urihttp://hdl.handle.net/10754/659512
dc.description.abstractAsymmetric catalysis with readily available, cheap, and non-toxic alkaline earth metal catalysts represents a sustainable alternative to conventional synthesis methodologies. In this context, we describe the development of a first MgII-catalyzed enantioselective hydroboration providing the products with excellent yields and enantioselectivities. NMR spectroscopy studies and DFT calculations provide insights into the reaction mechanism and the origin of the enantioselectivity which can be explained by a metal-ligand cooperative catalysis pathway involving a non-innocent ligand.
dc.description.sponsorshipB.M. and L.C. acknowledge King Abdullah University of Science and Technology (KAUST) for computational resources of the supercomputer Shaheen II
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201908012
dc.rightsArchived with thanks to Angewandte Chemie
dc.subjectAsymmetrische Reduktionen
dc.subjectDichtefunktionalrechnungen
dc.subjectHydroborierungen
dc.subjectKetone
dc.subjectMagnesium
dc.titleAsymmetric Magnesium-Catalyzed Hydroboration by Metal-Ligand Cooperative Catalysis
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAngewandte Chemie
dc.rights.embargodate2020-10-23
dc.eprint.versionPublisher's version PDF
dc.contributor.institutionInstitute of Organic ChemistryRWTH Aachen Landoltweg 1 52074 Aachen Germany
kaust.personMaity, Bholanath
kaust.personCavallo, Luigi
kaust.personRueping, Magnus
refterms.dateFOA2019-11-04T12:36:30Z
kaust.acknowledged.supportUnitsupercomputer Shaheen II


Files in this item

Thumbnail
Name:
Falconnet_et_al-2019-Angewandte_Chemie.pdf
Size:
1.299Mb
Format:
PDF
Description:
publisher's version

This item appears in the following Collection(s)

Show simple item record