Electrodeposition of Unary Oxide on a Bimetallic Hydroxide as a Highly Active and Stable Catalyst for Water Oxidation
Kim, Hyun Seok
KAUST DepartmentPhysical Science and Engineering (PSE) Division
Embargo End Date2020-08-27
Permanent link to this recordhttp://hdl.handle.net/10754/658630
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AbstractFor industrial-scale water electrolysis, development of a highly stable and active oxygen evolution reaction (OER) electrocatalyst is highly demanded. In this study, we report an efficient OER electrocatalyst of CeOx (unary oxide) and NiFe-OH (bimetallic hydroxide) electrochemically deposited on a macroporous nickel foam substrate. The synthesized electrocatalyst exhibits remarkably improved OER performance by reaching a current density of 100 mA cm-2 at a low overpotential of 280 mV, which is quite superior to that of most of the previously reported non-noble-metal-based OER electrocatalysts. Furthermore, the developed catalyst demonstrated a minor Tafel slope of 43.2 mV dec-1 with good stability under a large current at a continuous operation of 80 000 s in a strong alkaline electrolyte. Experimental observations revealed that the combination of CeOx and NiFe-OH accelerates the electroadsorption energies between the electrocatalyst surface and oxygen intermediates, considerably contributing to the OER enhancement. These results undoubtedly represent an important milestone toward the development of efficient OER electrocatalysts for applications as industrial water electrolyzers.
CitationBose, R., Karuppasamy, K., Rajan, H., Velusamy, D. B., Kim, H.-S., & Alfantazi, A. (2019). Electrodeposition of Unary Oxide on a Bimetallic Hydroxide as a Highly Active and Stable Catalyst for Water Oxidation. ACS Sustainable Chemistry & Engineering. doi:10.1021/acssuschemeng.9b03496
SponsorsThe authors acknowledge the financial support provided by Khalifa University, Abu Dhabi, United Arab Emirates. This work was also supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (No. 2017R1D1A1A09000823).
PublisherAmerican Chemical Society (ACS)