Show simple item record

Hydrodeoxygenation of raw bio-oil towards platform chemicals over FeMoP/zeolite catalysts

dc.contributor.authorHita, Idoia
dc.contributor.authorCordero-Lanzac, Tomás
dc.contributor.authorBonura, Giuseppe
dc.contributor.authorCannilla, Catia
dc.contributor.authorArandes, José M.
dc.contributor.authorFrusteri, Francesco
dc.contributor.authorBilbao, Javier
dc.date.accessioned2019-10-01T12:37:46Z
dc.date.available2019-10-01T12:37:46Z
dc.date.issued2019-08-09
dc.identifier.citationHita, I., Cordero-Lanzac, T., Bonura, G., Cannilla, C., Arandes, J. M., Frusteri, F., & Bilbao, J. (2019). Hydrodeoxygenation of raw bio-oil towards platform chemicals over FeMoP/zeolite catalysts. Journal of Industrial and Engineering Chemistry, 80, 392–400. doi:10.1016/j.jiec.2019.08.019
dc.identifier.doi10.1016/j.jiec.2019.08.019
dc.identifier.urihttp://hdl.handle.net/10754/656824
dc.description.abstractThe hydrodeoxygenation of raw bio-oil was investigated in a continuous fixed bed reactor over a series of FeMoP/zeolite catalysts, pursuing a maximized and stable production of phenolics and aromatics. After 5 h of reaction, the catalysts reach a pseudosteady activity state. The FeMoP/HZSM-5 catalyst yields the highest amount of carbon products (53.5 wt%) with the highest selectivity towards aromatics (13.6 wt%, dry basis) and phenolics (12.2 wt%), due to the synergy between the weak acidity of the FeMoP and the mild acidity of the HZSM-5 zeolite, which minimizes dehydration and gasification. The MFI framework allows the sweeping of coke precursors.
dc.description.sponsorshipThis work was carried out with the support of the Ministry of Economy and Competitiveness of the Spanish Government, some cofounded with ERDF funds (CTQ2015-67425-R), the Basque Government (IT1218-19) and the European Commission (Horizon H2020-MSCA RISE-2018, Contract No. 823745). Dr. Idoia Hita is grateful for her postdoctoral grant awarded by the Department of Education, University and Research of the Basque Government (POS_2015_1_0035). Authors thank Dr. Enrico Catizzone from UniCAL (Cosenza, Italy) for ICP-MS measurements.
dc.publisherElsevier BV
dc.relation.urlhttps://linkinghub.elsevier.com/retrieve/pii/S1226086X19304228
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Journal of Industrial and Engineering Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Industrial and Engineering Chemistry, [[Volume], [Issue], (2019-01-01)] DOI: 10.1016/j.jiec.2019.08.019 . © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectHydrodeoxygenation
dc.subjectBio-oil
dc.subjectAromatics
dc.subjectPhenolics
dc.subjectDeactivation
dc.subjectHZSM-5 zeolite
dc.titleHydrodeoxygenation of raw bio-oil towards platform chemicals over FeMoP/zeolite catalysts
dc.typeArticle
dc.contributor.departmentMultiscale Reaction Engineering, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia
dc.identifier.journalJournal of Industrial and Engineering Chemistry
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemical Engineering, University of the Basque Country (UPV/EHU), PO Box 644-48080, Bilbao, Spain
dc.contributor.institutionCNR-ITAE, Istituto di Tecnologie Avanzate per l'Energia “Nicola Giordano”, Via S. Lucia sopra Contesse, 5-98126 Messina, Italy
kaust.personHita, Idoia
refterms.dateFOA2019-10-03T11:33:34Z
dc.date.published-online2019-08-09
dc.date.published-print2019-08


Files in this item

Thumbnail
Name:
Manuscript_new.pdf
Size:
552.2Kb
Format:
PDF
Description:
Accepted manuscript
Download

This item appears in the following Collection(s)

Show simple item record