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dc.contributor.authorPan, Yupeng
dc.contributor.authorGuan, Chao
dc.contributor.authorLi, Huaifeng
dc.contributor.authorChakraborty, Priyanka
dc.contributor.authorZhou, Chunhui
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2019-08-18T13:35:56Z
dc.date.available2019-08-18T13:35:56Z
dc.date.issued2019-08-13
dc.identifier.citationPan, Y., Guan, C., Li, H., Chakraborty, P., Zhou, C., & Huang, K.-W. (2019). CO2 hydrogenation by phosphorus–nitrogen PN3P-pincer iridium hydride complexes: elucidation of the deactivation pathway. Dalton Transactions. doi:10.1039/c9dt01319a
dc.identifier.doi10.1039/c9dt01319a
dc.identifier.urihttp://hdl.handle.net/10754/656480
dc.description.abstractPN3P-Ir pincer hydride complexes were synthesized and characterized as catalysts and key intermediates in the direct hydrogenation of CO2 to formate under mild conditions. The formation of a dearomatized PN3P*-Ir(i)-CO species was identified as a plausible key process accountable for the loss of catalytic activity in the CO2 hydrogenation.
dc.description.sponsorshipThis work was supported by funding from the King Abdullah University of Science and Technology (KAUST).
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://xlink.rsc.org/?DOI=C9DT01319A
dc.relation.urlhttps://doi.org/10.1039/c9dt01319a
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
dc.rightsThis file is an open access version redistributed from: https://doi.org/10.1039/c9dt01319a
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/
dc.titleCO2 hydrogenation by phosphorus-nitrogen PN3P-pincer iridium hydride complexes: elucidation of the deactivation pathway.
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalDalton Transactions
dc.rights.embargodate2020-08-13
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionShenzhen Grubbs Institute, Southern University of Science and Technology (SUSTech), Shenzhen, 518055, P. R. China
kaust.personPan, Yupeng
kaust.personGuan, Chao
kaust.personLi, Huaifeng
kaust.personChakraborty, Priyanka
kaust.personZhou, Chunhui
kaust.personHuang, Kuo-Wei
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc1lrsqv
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc1jsrz1
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc228hwr
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc1jss03
refterms.dateFOA2020-09-21T11:12:13Z
display.relations<b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1lrsqv">10.5517/ccdc.csd.cc1lrsqv</a> HANDLE: <a href="http://hdl.handle.net/10754/664759">10754/664759</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1jsrz1">10.5517/ccdc.csd.cc1jsrz1</a> HANDLE: <a href="http://hdl.handle.net/10754/664760">10754/664760</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc228hwr">10.5517/ccdc.csd.cc228hwr</a> HANDLE: <a href="http://hdl.handle.net/10754/664761">10754/664761</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1jss03">10.5517/ccdc.csd.cc1jss03</a> HANDLE: <a href="http://hdl.handle.net/10754/664762">10754/664762</a></li></ul>


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