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dc.contributor.authorYao, Changguang
dc.contributor.authorZhang, Tonghuan
dc.contributor.authorZhou, Chunhui
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2019-08-18T13:31:16Z
dc.date.available2019-08-18T13:31:16Z
dc.date.issued2019-08-13
dc.identifier.citationYao, C., Zhang, T., Zhou, C., & Huang, K.-W. (2019). Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand. Dalton Transactions. doi:10.1039/c9dt03003d
dc.identifier.doi10.1039/c9dt03003d
dc.identifier.urihttp://hdl.handle.net/10754/656479
dc.description.abstractH2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.
dc.description.sponsorshipWe acknowledge the financial support from King Abdullah University of Science and Technology (KAUST).
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://xlink.rsc.org/?DOI=C9DT03003D
dc.relation.urlhttps://doi.org/10.1039/c9dt03003d
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
dc.rightsThis file is an open access version redistributed from: https://doi.org/10.1039/c9dt03003d
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/
dc.titleInterrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalDalton transactions (Cambridge, England : 2003)
dc.rights.embargodate2020-08-13
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionLab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, Peking University Shenzhen Graduate School, Shenzhen 518055, China
kaust.personYao, Changguang
kaust.personZhang, Tonghuan
kaust.personZhou, Chunhui
kaust.personHuang, Kuo-Wei
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc21hqjt
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc223gnb
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc223gm9
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc21hqs2
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc21hqkv
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc21hqhs
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc21hqpz
refterms.dateFOA2020-09-21T08:31:19Z
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