Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.
KAUST DepartmentChemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Embargo End Date2020-08-13
Permanent link to this recordhttp://hdl.handle.net/10754/656479
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AbstractH2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.
CitationYao, C., Zhang, T., Zhou, C., & Huang, K.-W. (2019). Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand. Dalton Transactions. doi:10.1039/c9dt03003d
SponsorsWe acknowledge the financial support from King Abdullah University of Science and Technology (KAUST).
PublisherRoyal Society of Chemistry (RSC)
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