Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation
Type
ArticleAuthors
Zulfiqar, SoniaMantione, Daniele
El Tall, Omar
Ruipérez, Fernando
Sarwar, Muhammad Ilyas
Rothenberger, Alexander
Mecerreyes, David
KAUST Department
Biological and Environmental Sciences and Engineering (BESE) DivisionChemical Science Program
Physical Science and Engineering (PSE) Division
Solids
Date
2019-06-04Online Publication Date
2019-06-04Print Publication Date
2019-06-17Embargo End Date
2020-06-17Permanent link to this record
http://hdl.handle.net/10754/656309
Metadata
Show full item recordAbstract
Herein, we describe the design and synthesis of novel pyridinium containing amide based poly(ionic liquid)s (PAPILs) for CO2 capture and separation. Additionally, a new and unique crystal structure of pyridinium containing diamine monomer [MDAP][TFSI] is also presented. PAPILs reveal potential for CO2/CH4 separation and isosteric heat of adsorption in the physisorption range.Citation
Zulfiqar, S., Mantione, D., El Tall, O., Ruipérez, F., Sarwar, M. I., Rothenberger, A., & Mecerreyes, D. (2019). Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation. ACS Sustainable Chemistry & Engineering, 7(12), 10241–10247. doi:10.1021/acssuschemeng.9b01903Sponsors
Dr. Sonia Zulfiqar is highly grateful for the financial support provided by Marie Curie IIF grant “NABPIL” (No. 629050) from the European Commission under the seventh Framework Programme (FP7-PEOPLE-2013-IIF). Dr. Fernando Ruipérez thanks the technical and human support provided by IZO-SGI, SGIker (UPV/EHU, MICINN, GV/EJ, ERDF, and ESF) for generous allocation of computational resources. Dr. Daniele Mantione is highly thankful for the support provided through EU project FP7-PEOPLE-212-ITN 316832-OLIMPIA. CCDC 1402084 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/data_request/cif, by e-mailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: (+44) 1223-336033.Publisher
American Chemical Society (ACS)Additional Links
http://pubs.acs.org/doi/10.1021/acssuschemeng.9b01903ae974a485f413a2113503eed53cd6c53
10.1021/acssuschemeng.9b01903