Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks
Alamer, Badriah Jaber
Hedhili, Mohamed N.
Emwas, Abdul-Hamid M.
Mohammed, Omar F.
KAUST DepartmentAdvanced Membranes & Porous Materials Center
Advanced Membranes and Porous Materials Research Center
Chemical Science Program
KAUST Catalysis Center
KAUST Catalysis Center (KCC)
KAUST Solar Center
KAUST Solar Center (KSC)
Materials Science and Engineering
Materials Science and Engineering Program
Physical Sciences and Engineering
Physical Sciences and Engineering (PSE) Division
Online Publication Date2019-05-28
Print Publication Date2019-06-19
Permanent link to this recordhttp://hdl.handle.net/10754/656042
MetadataShow full item record
AbstractHere, we demonstrate an approach to synthesizing and structurally characterizing three atomically precise anion-templated silver thiolate nanoclusters, two of which form one- and two-dimensional structural frameworks composed of bipyridine-linked nanocluster nodes (referred to as nanocluster-based frameworks, NCFs). We describe the critical role of the chloride (Cl−) template in controlling the nanocluster’s nuclearity with atomic precision and the effect of a single Ag atom difference in the nanocluster’s size in controlling the NCF dimensionality, modulating the optical properties, and improving the thermal stability. With atomically precise assembly and size control, nanoclusters could be widely adopted as building blocks for the construction of tunable cluster-based framework materials.
SponsorsThe authors sincerely thank the following people for their help and dedication at various stages of this project: Ayalew Assen, Karim Adil, and Osama Shekhah. The financial support for this work was provided by KAUST.
PublisherAmerican Chemical Society (ACS)