Negligible Energy Loss During Charge Generation in Small-Molecule/Fullerene Bulk-Heterojunction Solar Cells Leads to Open-Circuit Voltage over 1.10 V
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Ali I. Al-Naimi Petroleum Engineering Research Center (ANPERC)
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
KAUST Solar Center (KSC)
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
KAUST Grant NumberCRG-R2-13-BEAU-KAUST-1
Online Publication Date2019-03-29
Print Publication Date2019-04-22
Permanent link to this recordhttp://hdl.handle.net/10754/653036
MetadataShow full item record
AbstractSolution-processable small molecules (SMs) that can serve as donors in bulk-heterojunction (BHJ) solar cells are practical alternatives to their polymer counterparts. However, SM–fullerene blends commonly suffer severe voltage losses. In general, devices that reach open-circuit voltages (VOC) > 1 V yield low photocurrents in BHJ solar cells with fullerene acceptors (e.g., PC71BM) and modest power conversion efficiencies (PCEs). In this contribution, we report on the design, synthesis, and BHJ device characteristics of a new SM donor, 2F-DRCN5T, yielding a VOC of up to 1.10 V with PC71BM as the fullerene acceptor, while maintaining PCEs > 7% (over 8% achieved upon solvent-vapor-annealing (SVA) treatment). The negligible energy loss during charge generation (ΔECT), the deep-lying HOMO of 2F-DRCN5T inferred from its large ionization potential (IP), the high charge-transfer-state energy (ECT) of the blend, and a reduced nonradiative voltage loss account for the high VOC achieved in BHJ solar cells.
CitationBabics M, Duan T, Balawi AH, Liang R-Z, Cruciani F, et al. (2019) Negligible Energy Loss During Charge Generation in Small-Molecule/Fullerene Bulk-Heterojunction Solar Cells Leads to Open-Circuit Voltage over 1.10 V. ACS Applied Energy Materials 2: 2717–2722. Available: http://dx.doi.org/10.1021/acsaem.8b02020.
SponsorsThis publication is based upon work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award CRG-R2-13-BEAU-KAUST-1. The authors acknowledge concurrent support under Baseline Research Funding from KAUST. T.D. acknowledges financial support from National Natural Science Foundation of China (21702202).
PublisherAmerican Chemical Society (ACS)
JournalACS Applied Energy Materials