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dc.contributor.authorMagre, Marc
dc.contributor.authorMaity, Bholanath
dc.contributor.authorFalconnet, Alban
dc.contributor.authorCavallo, Luigi
dc.contributor.authorRueping, Magnus
dc.date.accessioned2019-04-15T11:52:00Z
dc.date.available2019-04-15T11:52:00Z
dc.date.issued2019-04-12
dc.identifier.citationMagre M, Maity B, Falconnet A, Cavallo L, Rueping M (2019) Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201902188.
dc.identifier.issn1433-7851
dc.identifier.doi10.1002/anie.201902188
dc.identifier.doi10.1002/ange.201902188
dc.identifier.urihttp://hdl.handle.net/10754/631875
dc.description.abstractA magnesium-catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been developed. The compatibility with many functional groups makes this magnesium catalyzed procedure attractive for late stage functionalization. Experimental mechanistic investigations and DFT calculations reveal insights into the reaction mechanism of the magnesium catalyzed protocol.
dc.description.sponsorshipB.M. and L.C. acknowledge King Abdullah University of Science and Technology (KAUST) for computational resources of the supercomputer Shaheen II.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/full/10.1002/anie.201902188
dc.rightsArchived with thanks to Angewandte Chemie International Edition
dc.subjectMagnesium
dc.subjectAlkynes
dc.subjectDFT
dc.subjectHydroboration
dc.subjectVinyl Borane
dc.titleMagnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAngewandte Chemie International Edition
dc.eprint.versionPost-print
dc.contributor.institutionInstitute of Organic Chemistry; RWTH Aachen; Landoltweg 1 52074 Aachen Germany
kaust.personMaity, Bholanath
kaust.personCavallo, Luigi
kaust.personRueping, Magnus
refterms.dateFOA2020-04-12T00:00:00Z
kaust.acknowledged.supportUnitSupercomputing Laboratory
dc.date.published-online2019-04-12
dc.date.published-print2019-05-20


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