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dc.contributor.authorHaque, Mohammed
dc.contributor.authorGandi, Appala
dc.contributor.authorMohanraman, Rajeshkumar
dc.contributor.authorWeng, Yakui
dc.contributor.authorDavaasuren, Bambar
dc.contributor.authorEmwas, Abdul-Hamid M.
dc.contributor.authorCombe, Craig
dc.contributor.authorBaran, Derya
dc.contributor.authorRothenberger, Alexander
dc.contributor.authorSchwingenschlögl, Udo
dc.contributor.authorAlshareef, Husam N.
dc.contributor.authorDong, Shuai
dc.contributor.authorWu, Tom
dc.date.accessioned2019-02-13T08:21:38Z
dc.date.available2019-02-13T08:21:38Z
dc.date.issued2019-02-07
dc.identifier.citationHaque MA, Gandi AN, Mohanraman R, Weng Y, Davaasuren B, et al. (2019) A 0D Lead-Free Hybrid Crystal with Ultralow Thermal Conductivity. Advanced Functional Materials: 1809166. Available: http://dx.doi.org/10.1002/adfm.201809166.
dc.identifier.issn1616-301X
dc.identifier.issn1616-3028
dc.identifier.doi10.1002/adfm.201809166
dc.identifier.urihttp://hdl.handle.net/10754/631033
dc.description.abstractOrganic–inorganic hybrid materials are of significant interest owing to their diverse applications ranging from photovoltaics and electronics to catalysis. Control over the organic and inorganic components offers flexibility through tuning their chemical and physical properties. Herein, it is reported that a new organic–inorganic hybrid, [Mn(C2H6OS)6]I4, with linear tetraiodide anions exhibit an ultralow thermal conductivity of 0.15 ± 0.01 W m−1 K−1 at room temperature, which is among the lowest values reported for organic–inorganic hybrid materials. Interestingly, the hybrid compound has a unique 0D structure, which extends into 3D supramolecular frameworks through nonclassical hydrogen bonding. Phonon band structure calculations reveal that low group velocities and localization of vibrational energy underlie the observed ultralow thermal conductivity, which could serve as a general principle to design novel thermal management materials.
dc.description.sponsorshipThe research reported in this publication was supported by funding from King Abdullah University of Science and Technology (KAUST).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/full/10.1002/adfm.201809166
dc.rightsArchived with thanks to Advanced Functional Materials
dc.subject0D
dc.subjecthybrid material
dc.subjecttetraiodide
dc.subjectthermal conductivity
dc.titleA 0D Lead-Free Hybrid Crystal with Ultralow Thermal Conductivity
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentComputational Physics and Materials Science (CPMS)
dc.contributor.departmentFunctional Nanomaterials and Devices Research Group
dc.contributor.departmentImaging and Characterization Core Lab
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentMaterial Science and Engineering Program
dc.contributor.departmentNMR
dc.contributor.departmentPhysical Characterization
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAdvanced Functional Materials
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Metallurgical and Materials EngineeringIndian Institute of Technology Jodhpur Karwad 342037 India
dc.contributor.institutionSchool of ScienceNanjing University of Posts and Telecommunications Nanjing 210023 China
dc.contributor.institutionDepartment of PhysicsSoutheast University Nanjing 211189 China
dc.contributor.institutionMaterials Synthesis and Processing (IEK-1)Institute for Energy and Climate ResearchForschungszentrum Jülich GmbH 52425 Jülich Germany
dc.contributor.institutionSchool of Materials Science and EngineeringUniversity of New South Wales (UNSW) Sydney NSW 2052 Australia
kaust.personHaque, Mohammed
kaust.personGandi, Appala
kaust.personMohanraman, Rajeshkumar
kaust.personDavaasuren, Bambar
kaust.personEmwas, Abdul-Hamid M.
kaust.personCombe, Craig
kaust.personBaran, Derya
kaust.personRothenberger, Alexander
kaust.personSchwingenschlögl, Udo
kaust.personAlshareef, Husam N.
refterms.dateFOA2019-02-13T08:23:01Z
dc.date.published-online2019-02-07
dc.date.published-print2019-03


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