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dc.contributor.authorYang, Peng
dc.contributor.authorzhao, Wenli
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorDong, Xiaochen
dc.contributor.authorAlshareef, Husam N.
dc.contributor.authorKhashab, Niveen M.
dc.date.accessioned2019-01-09T14:02:02Z
dc.date.available2019-01-09T14:02:02Z
dc.date.issued2019-01-04
dc.identifier.citationYang P, zhao W, Shkurenko A, Belmabkhout Y, Eddaoudi M, et al. (2019) Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality. Journal of the American Chemical Society. Available: http://dx.doi.org/10.1021/jacs.8b11998.
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.doi10.1021/jacs.8b11998
dc.identifier.urihttp://hdl.handle.net/10754/630779
dc.description.abstractSelf-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.
dc.description.sponsorshipAuthors acknowledge Dr. G. Mouchaham and Dr. O. El-Tall for technical assistance.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/jacs.8b11998
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see .
dc.titlePolyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentFunctional Nanomaterials and Devices Research Group
dc.contributor.departmentMaterial Science and Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentSmart Hybrid Materials (SHMs) lab
dc.identifier.journalJournal of the American Chemical Society
dc.eprint.versionPost-print
dc.contributor.institutionSchool of Physical and Mathematical Sciences, Nanjing Tech University, Nanjing 211800, China.
kaust.personYang, Peng
kaust.personShkurenko, Aleksander
kaust.personBelmabkhout, Youssef
kaust.personEddaoudi, Mohamed
kaust.personAlshareef, Husam N.
kaust.personKhashab, Niveen M.
display.relations<b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc20svd2">10.5517/ccdc.csd.cc20svd2</a> HANDLE: <a href="http://hdl.handle.net/10754/664416">10754/664416</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc20svc1">10.5517/ccdc.csd.cc20svc1</a> HANDLE: <a href="http://hdl.handle.net/10754/664417">10754/664417</a></li></ul>
dc.date.published-online2019-01-04
dc.date.published-print2019-02-06


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