Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality
Type
ArticleAuthors
Yang, Pengzhao, Wenli
Shkurenko, Aleksander

Belmabkhout, Youssef

Eddaoudi, Mohamed

Dong, Xiaochen
Alshareef, Husam N.

Khashab, Niveen M.

KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Functional Nanomaterials and Devices Research Group
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Smart Hybrid Materials (SHMs) lab
Date
2019-01-04Online Publication Date
2019-01-04Print Publication Date
2019-02-06Permanent link to this record
http://hdl.handle.net/10754/630779
Metadata
Show full item recordAbstract
Self-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.Citation
Yang P, zhao W, Shkurenko A, Belmabkhout Y, Eddaoudi M, et al. (2019) Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality. Journal of the American Chemical Society. Available: http://dx.doi.org/10.1021/jacs.8b11998.Sponsors
Authors acknowledge Dr. G. Mouchaham and Dr. O. El-Tall for technical assistance.Publisher
American Chemical Society (ACS)Additional Links
https://pubs.acs.org/doi/10.1021/jacs.8b11998Relations
Is Supplemented By:- [Dataset]
. DOI: 10.5517/ccdc.csd.cc20svd2 HANDLE: 10754/664416
- [Dataset]
. DOI: 10.5517/ccdc.csd.cc20svc1 HANDLE: 10754/664417
ae974a485f413a2113503eed53cd6c53
10.1021/jacs.8b11998