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    Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality

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    Type
    Article
    Authors
    Yang, Peng
    zhao, Wenli
    Shkurenko, Aleksander cc
    Belmabkhout, Youssef cc
    Eddaoudi, Mohamed cc
    Dong, Xiaochen
    Alshareef, Husam N. cc
    Khashab, Niveen M. cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Functional Nanomaterials and Devices Research Group
    Material Science and Engineering Program
    Physical Science and Engineering (PSE) Division
    Smart Hybrid Materials (SHMs) lab
    Date
    2019-01-04
    Online Publication Date
    2019-01-04
    Print Publication Date
    2019-02-06
    Permanent link to this record
    http://hdl.handle.net/10754/630779
    
    Metadata
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    Abstract
    Self-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.
    Citation
    Yang P, zhao W, Shkurenko A, Belmabkhout Y, Eddaoudi M, et al. (2019) Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality. Journal of the American Chemical Society. Available: http://dx.doi.org/10.1021/jacs.8b11998.
    Sponsors
    Authors acknowledge Dr. G. Mouchaham and Dr. O. El-Tall for technical assistance.
    Publisher
    American Chemical Society (ACS)
    Journal
    Journal of the American Chemical Society
    DOI
    10.1021/jacs.8b11998
    Additional Links
    https://pubs.acs.org/doi/10.1021/jacs.8b11998
    Relations
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc20svd2 HANDLE: 10754/664416
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc20svc1 HANDLE: 10754/664417
    ae974a485f413a2113503eed53cd6c53
    10.1021/jacs.8b11998
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program; Material Science and Engineering Program

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