Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis
Type
ArticleKAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2018-10-11Online Publication Date
2018-10-11Print Publication Date
2018-11-05Permanent link to this record
http://hdl.handle.net/10754/630581
Metadata
Show full item recordAbstract
Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.Citation
Muralirajan K, Kancherla R, Rueping M (2018) Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis. Angewandte Chemie International Edition 57: 14787–14791. Available: http://dx.doi.org/10.1002/anie.201808427.Sponsors
The authors acknowledge KAUST for financial support. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC grant agreement number 617044 (SunCatChem).Publisher
WileyJournal
Angewandte ChemieAdditional Links
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201808427ae974a485f413a2113503eed53cd6c53
10.1002/anie.201808427