Surface organometallic chemistry in heterogeneous catalysis

Samantaray, Manoja; Pump, Eva; Bendjeriou-Sedjerari, Anissa; D’Elia, Valerio; Pelletier, Jeremie; Guidotti, Matteo; Psaro, Rinaldo; Basset, Jean-Marie

Surface organometallic chemistry in heterogeneous catalysis

Type

Article

Authors

Samantaray, Manoja
Pump, Eva

Bendjeriou-Sedjerari, Anissa
D’Elia, Valerio

Pelletier, Jeremie

Guidotti, Matteo
Psaro, Rinaldo

Basset, Jean-Marie

KAUST Department

Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Technology Transfer

Date

2018

Abstract

The broad challenges of energy and environment have become a main focus of research efforts to develop more active and selective catalytic systems for key chemical transformations. Surface organometallic chemistry (SOMC) is an established concept, associated with specific tools, for the design, preparation and characterization of well-defined single-site catalysts. The objective is to enter a catalytic cycle through a presumed catalytic intermediate prepared from organometallic or coordination compounds to generate well defined surface organometallic fragments (SOMFs) or surface coordination fragments (SCFs). These notions are the basis of the

Citation

Samantaray MK, Pump E, Bendjeriou-Sedjerari A, D’Elia V, Pelletier JDA, et al. (2018) Surface organometallic chemistry in heterogeneous catalysis. Chemical Society Reviews 47: 8403–8437. Available: http://dx.doi.org/10.1039/c8cs00356d.

Acknowledgements

We thank KAUST for financial and human support and all our friends who helped us to develop the field in Europe, China, America, Japan, and Saudi Arabia. VDE thanks the Thailand Research Fund for generous support (Grant No. RSA6080059).