Photothermally Responsive Inks for Inkjet-Printing Secure Information
Online Publication Date2018-08-08
Print Publication Date2018-09
Permanent link to this recordhttp://hdl.handle.net/10754/630475
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Abstract2D patterns of photothermally responsive near-infrared (NIR) absorbing gold nanostars (GNS), coated with multiple charged polymer layers, are inkjet-printed on a glass surface. The shape of the localized surface plasmon resonance (LSPR) NIR absorption bands in the printed patterns loses its peaked form due to plasmon coupling, unless GNS are enveloped in multiple coating layers, keeping the inter-GNS distance sufficiently large. In the latter case, the photothermal temperature increase (ΔT) induced by the NIR laser irradiation follows a ΔT versus irradiation wavelength (λirr) profile with the same sharply peaked shape of the LSPR bands of the liquid ink. With this result, a new paradigm for inkjet-writing secure information is introduced, as an alternative to the current methods based on direct visual inspection of printed patterns. While the printed ink patterns of GNS with different coatings are visually indistinguishable despite their different NIR absorption spectrum, their photothermal response changes dramatically with λirr. This allows either to write and read simple information using a single λirr (YES answer for ΔT > threshold) or to use multiple λirr to write and read complex information like thermal bar codes and anti-counterfeit signatures.
CitationChirico G, Dacarro G, O’Regan C, Peltonen J, Sarfraz J, et al. (2018) Photothermally Responsive Inks for Inkjet-Printing Secure Information. Particle & Particle Systems Characterization 35: 1800095. Available: http://dx.doi.org/10.1002/ppsc.201800095.
SponsorsThe research project “Photothermally responsive inks for inkjet-printing secure informations” was granted by Università di Pavia, Blue Sky Research 2017 (BSR1774514). C.O'R. acknowledges financial support received from the King Abdullah University of Science and Technology (KAUST) baseline funding of Prof. Andrea Falqui. Thanks are due for SEM imaging to Prof. Emilano Fratini and CSGI, Department of Chemistry “Ugo Schiff,” Università di Firenze, Italy, and for TGA measurements to Prof. Chiara Milanese, Dipartimento di Chimica, Università di Pavia.