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dc.contributor.authorJiang, Yu
dc.contributor.authorZhang, Zhen
dc.contributor.authorWang, De
dc.contributor.authorHadjichristidis, Nikos
dc.date.accessioned2018-12-31T13:09:00Z
dc.date.available2018-12-31T13:09:00Z
dc.date.issued2018-04-13
dc.identifier.citationJiang Y, Zhang Z, Wang D, Hadjichristidis N (2018) An Efficient and General Strategy toward the Synthesis of Polyethylene-Based Cyclic Polymers. Macromolecules 51: 3193–3202. Available: http://dx.doi.org/10.1021/acs.macromol.8b00333.
dc.identifier.issn0024-9297
dc.identifier.issn1520-5835
dc.identifier.doi10.1021/acs.macromol.8b00333
dc.identifier.urihttp://hdl.handle.net/10754/630414
dc.description.abstractA novel strategy toward well-defined polyethylene-based cyclic homo/copolymers is presented. Tris(3-(anthracen-9-ylmethoxy)propyl)borane, prepared by hydroboration of 9-((allyloxy)methyl)anthracene with BH, was used to initiate the polyhomologation of dimethylsulfoxonium methylide to afford well-defined anthracene-teminated linear polyethylene (PE). The azido and alkynyl groups at α and ω positions of the PE chain were introduced via the anthracene/maleimide Diels-Alder (D-A) reaction and esterification, respectively. Subsequent intramolecular
dc.description.sponsorshipResearch reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acs.macromol.8b00333
dc.titleAn Efficient and General Strategy toward the Synthesis of Polyethylene-Based Cyclic Polymers
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentPolymer Synthesis Laboratory
dc.identifier.journalMacromolecules
kaust.personJiang, Yu
kaust.personZhang, Zhen
kaust.personWang, De
kaust.personHadjichristidis, Nikos
dc.date.published-online2018-04-13
dc.date.published-print2018-04-24


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