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dc.contributor.authorCortecchia, D.
dc.contributor.authorNeutzner, S.
dc.contributor.authorYin, Jun
dc.contributor.authorSalim, T.
dc.contributor.authorSrimath Kandada, A. R.
dc.contributor.authorBruno, A.
dc.contributor.authorLam, Y. M.
dc.contributor.authorMartí-Rujas, J.
dc.contributor.authorPetrozza, A.
dc.contributor.authorSoci, C.
dc.date.accessioned2018-12-20T12:07:48Z
dc.date.available2018-12-20T12:07:48Z
dc.date.issued2018-11-26
dc.identifier.citationCortecchia D, Neutzner S, Yin J, Salim T, Srimath Kandada AR, et al. (2018) Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites. APL Materials 6: 114207. Available: http://dx.doi.org/10.1063/1.5045782.
dc.identifier.issn2166-532X
dc.identifier.doi10.1063/1.5045782
dc.identifier.urihttp://hdl.handle.net/10754/630333
dc.description.abstractRuddlesden-Popper perovskites are highly attractive for light-emitting and photonic applications. In these exceptionally deformable frameworks, structural properties strongly impact on the energetic landscape of the material; thus, it is crucial to establish a correlation between the structure and optoelectronic characteristics. Here, we study the structural transformations induced by phase transitions in the butylammonium-based series (BA)(MA)[PbI] (n = 1 and n = 2). We show how thermally driven lattice contraction and changes in crystal packing affect their characteristic absorption and photoluminescence. These findings provide new insights for functional perovskites’ rational design, highlighting the possibility to tune the structural properties through external stimuli to control their functionalities on-demand.
dc.description.sponsorshipThis work was supported by the Ministry of Education (Ref. Nos. MOE2016-T1-1-164 and MOE2011-T3-1-005) and the National Research Foundation (Ref. No. NRF-CRP14-2014-03) of Singapore. We thank the financial support from the EU Horizon 2020 Research and Innovation Programme under Grant Agreement N. 643238 (SYNCHRONICS). We also acknowledge the CARIPLO Foundation (IPER-LUCE No. 2015-0080) for funding. Computational work was supported by Supercomputing Laboratory at King Abdullah University of Science and Technology.
dc.publisherAIP Publishing
dc.relation.urlhttps://aip.scitation.org/doi/10.1063/1.5045782
dc.rightsAll article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectBand gap
dc.subjectCrystal lattices
dc.subjectX-ray diffraction
dc.subjectPhotoluminescence
dc.subjectChemical compounds and components
dc.subjectLattice dynamics
dc.subjectPhase transitions
dc.subjectPerovskites
dc.subjectDifferential scanning
dc.subjectcalorimetry
dc.titleStructure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites
dc.typeArticle
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAPL Materials
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionIstituto Italiano di Tecnologia, Centre for Nano Science and Technology (CNST@PoliMi), Milan, 20133, , Italy
dc.contributor.institutionEnergy Research Institute @NTU (ERI@N), Nanyang Technological University, 50 Nanyang Drive, Singapore, 6375532, , Singapore
dc.contributor.institutionInterdisciplinary Graduate School, Nanyang Technological University, Singapore, 639798, , Singapore
dc.contributor.institutionSchool of Material Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, , Singapore
dc.contributor.institutionDipartimento di Chimica Materiali e Ingegneria Chimica, “Giulio Natta,” Politecnico di Milano, Via Luigi Mancinelli 7, Milan, 20131, , Italy
dc.contributor.institutionDivision of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, 637371, , Singapore
kaust.personYin, Jun
refterms.dateFOA2018-12-20T12:26:31Z
dc.date.published-online2018-11-26
dc.date.published-print2018-11


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All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Except where otherwise noted, this item's license is described as All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).