Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex
Mohandas, Janet Chakkamadathil
Hamieh, Ali Imad Ali
Kavitake, Santosh Giridhar
KAUST DepartmentAli I. Al-Naimi Petroleum Engineering Research Center (ANPERC)
Chemical Science Program
Imaging and Characterization Core Lab
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Physical Science and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/629596
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AbstractA novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl (TaMe5) has been described, by direct demethylation using B(C6F5)3 reagent. The aforesaid higher valent cationic tantalum complex was characterized precisely by liquid state 1H-NMR, 13C-NMR, and 1H-13C-NMR correlation spectroscopy.
CitationDey R, Mohandas J, Samantaray M, Hamieh A, Kavitake S, et al. (2018) Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex. Catalysts 8: 507. Available: http://dx.doi.org/10.3390/catal8110507.
SponsorsThis work was supported by funds from King Abdullah University of Science and Technology (KAUST) office of sponsored research (OSR). R.D. thanks National Institute of Technology, Calicut for financial support. A.P. thanks the Spanish MINECO for a project CTQ2014-59832-JIN. The authors acknowledge the KAUST Nuclear Magnetic Resonance Core Lab and the technical assistance of Xianrong Guo.
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