Measurement of laminar burning velocity of n-pentanol + air mixtures at elevated temperatures and a skeletal kinetic model
KAUST DepartmentChemical Engineering Program
Clean Combustion Research Center
Combustion and Pyrolysis Chemistry (CPC) Group
Physical Science and Engineering (PSE) Division
Online Publication Date2018-10-01
Print Publication Date2019-02
Permanent link to this recordhttp://hdl.handle.net/10754/628899
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AbstractLong chain alcohols are potential fuels for engine applications, however, their combustion characteristics need to be adequately investigated compared to short chain alcohols (C1–C4), especially at high mixture temperatures, and other conditions relevant to engine temperatures. In the present work, meso-scale diverging channel method has been used to measure the laminar burning velocity of n-pentanol + air mixtures at elevated temperatures due to existence of very limited data at higher mixture temperatures (∼473 K). The present experiments are carried out at atmospheric pressure with unburnt mixture temperature varying up to 560 K. The dependence of laminar burning velocity on temperature was correlated using the power law: , where α is the temperature exponent. The results show the existence of a minimum value of α for slightly rich mixtures. A reduced kinetic model based on the previous detailed kinetic model of Sarathy (2014) for C1–C5 straight-chain alcohols was generated with 199 species and 1427 reactions. Experimental results of laminar burning velocity of n-pentanol + air mixtures at high temperatures were compared with the present model and other kinetic models from the literature. The skeletal model accurately reproduces the measurements at various conditions.
CitationKatoch A, Alfazazi A, Sarathy SM, Chauhan A, Kumar R, et al. (2019) Measurement of laminar burning velocity of n-pentanol + air mixtures at elevated temperatures and a skeletal kinetic model. Fuel 237: 10–17. Available: http://dx.doi.org/10.1016/j.fuel.2018.09.145.
SponsorsThe first author would like to acknowledge the financial support for this work from Department of Science and Technology, Govt. of India wide grant no. SB/S3/COMB-001/(2014). Research conducted by AF and SMS of Clean Combustion Research Center was supported by competitive research funding from King Abdullah University of Science and Technology (KAUST).