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dc.contributor.authorJia, Jiaqi
dc.contributor.authorHo, Yee Ann
dc.contributor.authorBülow, Raoul F.
dc.contributor.authorRueping, Magnus
dc.date.accessioned2018-09-27T07:12:25Z
dc.date.available2018-09-27T07:12:25Z
dc.date.issued2018-08-27
dc.identifier.citationJia J, Ho YA, Bülow RF, Rueping M (2018) Brønsted Base Assisted Photoredox Catalysis: Proton Coupled Electron Transfer for Remote C−C Bond Formation via Amidyl Radicals. Chemistry - A European Journal 24: 14054–14058. Available: http://dx.doi.org/10.1002/chem.201802907.
dc.identifier.issn0947-6539
dc.identifier.doi10.1002/chem.201802907
dc.identifier.urihttp://hdl.handle.net/10754/628808
dc.description.abstractThe synthesis of alkyne- and alkene-decorated lactams has been achieved through a photoredox-initiated radical cascade reaction. The developed Brønsted base assisted, photoredox-catalyzed, intramolecular 5-exo-trig cyclization/intermolecular radical addition/elimination reaction provides facile access to functionalized γ-lactams, with good functional group tolerance and high yields.
dc.description.sponsorshipY.A.H. would like to thank Deutscher Akademischer Austauschdienst (DAAD) for a doctoral scholarship. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007–2013)/ERC Grant Agreement no. 617044 (SunCatChem).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/full/10.1002/chem.201802907
dc.rightsArchived with thanks to Chemistry - A European Journal
dc.subjectBrønsted base
dc.subjectlactam derivatives
dc.subjectphotoredox catalysis
dc.subjectproton-coupled electron transfer (PCET)
dc.subjectradical reactions
dc.subjectsulfonyl radical
dc.titleBrønsted Base Assisted Photoredox Catalysis: Proton Coupled Electron Transfer for Remote C−C Bond Formation via Amidyl Radicals
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalChemistry - A European Journal
dc.eprint.versionPost-print
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen; Landoltweg 1 52074 Aachen Germany
kaust.personRueping, Magnus
refterms.dateFOA2018-09-27T12:54:41Z
dc.date.published-online2018-08-27
dc.date.published-print2018-09-20


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