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dc.contributor.authorWang, Xuerui
dc.contributor.authorKarakilic, Pelin
dc.contributor.authorLiu, Xinlei
dc.contributor.authorShan, Meixia
dc.contributor.authorNijmeijer, Arian
dc.contributor.authorWinnubst, Louis
dc.contributor.authorGascon, Jorge
dc.contributor.authorKapteijn, Freek
dc.date.accessioned2018-09-16T12:40:38Z
dc.date.available2018-09-16T12:40:38Z
dc.date.issued2018-09-11
dc.identifier.citationWang X, Karakilic P, Liu X, Shan M, Nijmeijer A, et al. (2018) One-pot synthesis of high-flux b-oriented MFI zeolite membranes for Xe recovery. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.8b12613.
dc.identifier.issn1944-8244
dc.identifier.issn1944-8252
dc.identifier.doi10.1021/acsami.8b12613
dc.identifier.urihttp://hdl.handle.net/10754/628726
dc.description.abstractWe demonstrate that b-oriented MFI zeolite membranes can be manufactured by in-situ crystallization using an intermediate amorphous SiO2 layer. The improved in-plane growth by using a zeolite growth modifier leads to fusion of independent crystals and eliminates boundary gaps, giving good selectivity in the separation of CO2/Xe mixtures. The fast diffusion of CO2 dominates the overall membrane selectivity towards CO2/Xe mixture. Because of the straight and short [010] channels, the obtained CO2 permeation fluxes are several orders of magnitude higher than those of carbon molecular sieving membranes and polymeric membranes, opening opportunities for Xe recovery from waste anaesthetic gas.
dc.description.sponsorshipThis work is financially supported by STW, The Netherlands (Project number 13941). The authors thank Bart van der Linden (Delft University of Technology, TUD), Willy Rook (TUD) and Liliana Baron (TUD) for their help with gas separation performance and gas uptake measurements.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acsami.8b12613
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acsami.8b12613.
dc.subjectMFI zeolite membrane
dc.subjectgas separation
dc.subjectxenon
dc.subjectanaesthetic
dc.subjectcarbon dioxide
dc.titleOne-pot synthesis of high-flux b-oriented MFI zeolite membranes for Xe recovery
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalACS Applied Materials & Interfaces
dc.eprint.versionPost-print
dc.contributor.institutionChemical Engineering Department, Delft University of Technology, Van der Maasweg 9, 2629 HZ Delft, The Netherlands
dc.contributor.institutionDepartment Inorganic Membranes, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands
kaust.personGascon, Jorge
refterms.dateFOA2018-09-16T13:12:53Z
dc.date.published-online2018-09-11
dc.date.published-print2018-10-03


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