Mohammed, Omar F.
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Nanomaterials Lab (FuNL)
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Material Science and Engineering Program
Nanostructured Functional Materials (NFM) laboratory
Physical Science and Engineering (PSE) Division
Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
Online Publication Date2018-09-05
Print Publication Date2018-09-20
Permanent link to this recordhttp://hdl.handle.net/10754/628706
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AbstractZero-dimensional (0D) perovskites have recently opened a new frontier in device engineering for light conversion technologies due to their unprecedented high photoluminescence quantum yield as solids. Although many experimental and theoretical efforts have been made to understand their optical behavior, the origin of their green emission is still opaque. Here, we develop a complete experimental and theoretical picture of point defects in Cs-Pb-Br perovskites and demonstrate that bromide vacancies (VBr) in prototype 0D perovskite Cs4PbBr6 have low formation energy and a relevant defect level to contribute to the mid-gap radiative state. Moreover, the state-of-the-art characterizations including atomic-resolution electron imaging not only confirm the purity of 0D-phase of Br-deficient green-emissive Cs4PbBr6 nanocrystals (NCs), but also exclude the presence of CsPbBr3 NCs impurities. Our findings provide robust evidence for defect-induced green luminescence in 0D perovskite nanoscrystals, which helps extend the scope of the utility of these bulk 0D quantum materials in optoelectronic applications.
CitationYin J, Yang H, Song K, El-Zohry AM, Han Y, et al. (2018) Point Defects and Green Emission in Zero-Dimensional Perovskites. The Journal of Physical Chemistry Letters: 5490–5495. Available: http://dx.doi.org/10.1021/acs.jpclett.8b02477.
SponsorsThis work was supported by the King Abdullah University of Science and Technology (KAUST) and by the Georgia Research Alliance. J.Y., J.-L.B., and O.F.M. acknowledge the Supercomputing Laboratory at KAUST for their computational and storage resources as well as their gracious assistance.
PublisherAmerican Chemical Society (ACS)