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Hydrogenation of CO2\n-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis

dc.contributor.authorZubar, Viktoriia
dc.contributor.authorLebedev, Yury
dc.contributor.authorAzofra Mesa, Luis
dc.contributor.authorCavallo, Luigi
dc.contributor.authorEl-Sepelgy, Osama
dc.contributor.authorRueping, Magnus
dc.date.accessioned2018-09-06T06:47:07Z
dc.date.available2018-09-06T06:47:07Z
dc.date.issued2018-09-03
dc.identifier.citationZubar V, Lebedev Y, Azofra LM, Cavallo L, El-Sepelgy O, et al. (2018) Hydrogenation of CO2\n-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201805630.
dc.identifier.issn1433-7851
dc.identifier.doi10.1002/anie.201805630
dc.identifier.doi10.1002/ange.201805630
dc.identifier.urihttp://hdl.handle.net/10754/628519
dc.description.abstractThe first base-metal-catalysed hydrogenation of CO2 -derived carbonates to alcohols is presented. The reaction proceeds under mild conditions in the presence of a well-defined manganese complex with a loading as low as 0.25 mol %. The non-precious-metal homogenous catalytic system provides an indirect route for the conversion of CO2 into methanol with the co-production of value-added (vicinal) diols in yields of up to 99 %. Experimental and computational studies indicate a metal-ligand cooperative catalysis mechanism.
dc.description.sponsorshipL.M.A. and L.C. thank King Abdullah University of Science and Technology (KAUST) for support. Gratitude is also due to the KAUST Supercomputing Laboratory for providing computational resources and granting access to the supercomputer Shaheen II.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/full/10.1002/anie.201805630
dc.rightsArchived with thanks to Angewandte Chemie International Edition
dc.subjectCarbon dioxide
dc.subjectManganese
dc.subjectReduction
dc.subjectMethanol
dc.subjectCarbonates
dc.titleHydrogenation of CO2\n-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAngewandte Chemie International Edition
dc.eprint.versionPost-print
dc.contributor.institutionInstitute of Organic Chemistry; RWTH Aachen University; Landoltweg 1 52074 Aachen Germany
kaust.personLebedev, Yury
kaust.personAzofra Mesa, Luis
kaust.personCavallo, Luigi
kaust.personRueping, Magnus
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc20z4gm
refterms.dateFOA2018-09-06T07:26:44Z
display.relations<b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc20z4gm">10.5517/ccdc.csd.cc20z4gm</a> HANDLE: <a href="http://hdl.handle.net/10754/664187">10754/664187</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc20z4gm">10.5517/ccdc.csd.cc20z4gm</a> HANDLE: <a href="http://hdl.handle.net/10754/664188">10754/664188</a></li></ul>
dc.date.published-online2018-09-03
dc.date.published-print2018-10-08


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