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    Hydrogenation of CO2\n-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis

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    Type
    Article
    Authors
    Zubar, Viktoriia
    Lebedev, Yury cc
    Azofra Mesa, Luis cc
    Cavallo, Luigi cc
    El-Sepelgy, Osama
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2018-09-03
    Online Publication Date
    2018-09-03
    Print Publication Date
    2018-10-08
    Permanent link to this record
    http://hdl.handle.net/10754/628519
    
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    Abstract
    The first base-metal-catalysed hydrogenation of CO2 -derived carbonates to alcohols is presented. The reaction proceeds under mild conditions in the presence of a well-defined manganese complex with a loading as low as 0.25 mol %. The non-precious-metal homogenous catalytic system provides an indirect route for the conversion of CO2 into methanol with the co-production of value-added (vicinal) diols in yields of up to 99 %. Experimental and computational studies indicate a metal-ligand cooperative catalysis mechanism.
    Citation
    Zubar V, Lebedev Y, Azofra LM, Cavallo L, El-Sepelgy O, et al. (2018) Hydrogenation of CO2\n-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201805630.
    Sponsors
    L.M.A. and L.C. thank King Abdullah University of Science and Technology (KAUST) for support. Gratitude is also due to the KAUST Supercomputing Laboratory for providing computational resources and granting access to the supercomputer Shaheen II.
    Publisher
    Wiley
    Journal
    Angewandte Chemie International Edition
    DOI
    10.1002/anie.201805630
    10.1002/ange.201805630
    Additional Links
    https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201805630
    Relations
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc20z4gm HANDLE: 10754/664187
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc20z4gm HANDLE: 10754/664188
    ae974a485f413a2113503eed53cd6c53
    10.1002/anie.201805630
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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