KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
Environmental Science and Engineering Program
Water Desalination and Reuse Research Center (WDRC)
Online Publication Date2018-08-22
Print Publication Date2019-01
Permanent link to this recordhttp://hdl.handle.net/10754/628494
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AbstractHypothesis: \nCoating-free approaches to achieve liquid repellent, or omniphobic, surfaces could exploit inexpensive intrinsically wetting materials, such as polyethylene terephthalate and nylon, for applications such as liquid-vapor extraction and drag reduction. However, it is not clear whether the existing criteria for assessing coating-based omniphobicity, based on apparent contact angles, would be reliable for coating-free approaches, especially considering localized defects/damages during manufacturing and usage. \nExperiments: \nWe assessed the omniphobicity of silica surfaces adorned with arrays of doubly reentrant pillars, cavities, and hybrid designs with sessile drops and on immersion in water and hexadecane through contact angle goniometry and confocal microscopy, respectively. \nFindings: \nWe demonstrate that the assessment of omniphobicity of surfaces derived from intrinsically wetting materials can be misleading, if solely based on the measurement of contact angles. Specifically, localized defects in microtextures consisting of pillars may lead to the spontaneous loss of omniphobicity and detecting them through contact angles can be difficult. We also demonstrate that the immersion of those surfaces into probe liquids may serve as a simple and quick ‘litmus’ test for omniphobicity. Thus, immersion as additional criterion for omniphobicity might prove itself useful in the context of large-scale manufacturing.
CitationArunachalam S, Das R, Nauruzbayeva J, Domingues EM, Mishra H (2018) Assessing Omniphobicity by Immersion. Journal of Colloid and Interface Science. Available: http://dx.doi.org/10.1016/j.jcis.2018.08.059.
SponsorsHM acknowledges funding from King Abdullah University of Science and Technology (KAUST). The authors thank Mr. Ulrich Buttner and Mr. Ahad Sayed from the KAUST Core Labs for their assistance with the microfabrication process; we also gratefully acknowledge Dr. Yair Kaufman (Ben-Gurion University of the Negev) for the fruitful discussions. We also acknowledge Mr. Xavier Pita, Scientific Illustrator at KAUST, for preparing Figure 4 and the Table of Contents’ figure, and Dr. Elisabeth Lutanie for assistance in scientific editing.