Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction

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Type
Article
Authors
Huang, Kuo-Wei cc
Li, Huaifeng cc
Goncalves, Theo
Zhao, Qianyi
Gong, Dirong
Lai, Zhiping cc
Wang, Zhi-Xiang
Zheng, Junrong
KAUST Department
Advanced Membranes and Porous Materials Research Center
Chemical Engineering Program
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2018
Permanent link to this record
http://hdl.handle.net/10754/628474

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Abstract
A dearomatized PN3P*-nickel hydride complex has been prepared by oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selectvie methylation and formylation of amines with CO2 were demonstrated by such PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.
Citation
Li H, Gonçalves TP, Zhao Q, Gong D, Lai Z, et al. (2018) Diverse catalytic reactivity of a dearomatized PN3P*–nickel hydride pincer complex towards CO2 reduction. Chemical Communications. Available: http://dx.doi.org/10.1039/c8cc05948a.
Publisher
Royal Society of Chemistry (RSC)
Journal
Chemical Communications
DOI
10.1039/c8cc05948a
Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC05948A#!divAbstract
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Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC)