Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Engineering Program
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/628474
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AbstractA dearomatized PN3P*-nickel hydride complex has been prepared by oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selectvie methylation and formylation of amines with CO2 were demonstrated by such PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.
CitationLi H, Gonçalves TP, Zhao Q, Gong D, Lai Z, et al. (2018) Diverse catalytic reactivity of a dearomatized PN3P*–nickel hydride pincer complex towards CO2 reduction. Chemical Communications. Available: http://dx.doi.org/10.1039/c8cc05948a.
PublisherRoyal Society of Chemistry (RSC)
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