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dc.contributor.authorSabetghadam, Anahid
dc.contributor.authorLiu, Xinlei
dc.contributor.authorOrsi, Angelica
dc.contributor.authorLozinska, Magdalena
dc.contributor.authorJohnson, Timothy
dc.contributor.authorJansen, Kaspar
dc.contributor.authorWright, Paul
dc.contributor.authorCarta, Mariolino
dc.contributor.authorMcKeown, Neil
dc.contributor.authorKapteijn, Freek
dc.contributor.authorGascon, Jorge
dc.date.accessioned2018-09-03T13:21:10Z
dc.date.available2018-09-03T13:21:10Z
dc.date.issued2018-08-08
dc.identifier.citationSabetghadam A, Liu X, Orsi AF, Lozinska MM, Johnson T, et al. (2018) Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping. Chemistry - A European Journal 24: 12796–12800. Available: http://dx.doi.org/10.1002/chem.201803006.
dc.identifier.issn0947-6539
dc.identifier.doi10.1002/chem.201803006
dc.identifier.urihttp://hdl.handle.net/10754/628402
dc.description.abstractMembrane separation for gas purification is an energy-efficient and environment-friendly technology. However, the development of high performance membranes is still a great challenge. In principle, mixed matrix membranes (MMMs) have the potential to overcome current materials limitations, but in practice there is no straightforward method to match the properties of fillers and polymers (the main components of MMMs) in such a way that the final membrane performance reflects the high performance of the microporous filler and the processability of the continuous polymer phase. This issue is especially important when high flux polymers are utilized. In this work, we demonstrate that the use of small amounts of a glassy polymer in combination with high performance PIM-1 allow for the preparation of MOF based MMMs with superior separation properties and low aging rates under humid conditions, meeting the commercial target for post-combustion CO2 capture.
dc.description.sponsorshipThe authors gratefully acknowledge the financial support from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013), M4CO2 project (608490).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803006
dc.rightsArchived with thanks to Chemistry - A European Journal
dc.subjectMembranes
dc.subjectmicroporous polymer
dc.subjectmetal-organic frameworks
dc.titleTowards High Performance MOF - Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging via Polymer Doping
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemistry - A European Journal
dc.eprint.versionPost-print
dc.contributor.institutionCatalysis Engineering, Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629HZ Delft, The Netherlands.
dc.contributor.institutionEaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, Fife, KY16 9ST, United Kingdom.
dc.contributor.institutionJohnson Matthey Technology Centre, Blount’s Court Road, Sonning Common, Reading, RG4 9NH, United Kingdom.
dc.contributor.institutionEmerging Materials, Department of Design Engineering, Delft University of Technology, Landbergstraat 15, 2628 CE Delft, The Netherlands.
dc.contributor.institutionDepartment of Chemistry, College of Science, Swansea University, Grove Building, Singleton Park, Swansea, SA2 8PP, United Kingdom.
dc.contributor.institutionEaStCHEM, School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh, Scotland EH93FJ, United Kingdom.
kaust.personGascon, Jorge
refterms.dateFOA2018-09-10T13:49:23Z
dc.date.published-online2018-08-08
dc.date.published-print2018-09-03


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