Reversible Switching and Recycling of Adaptable Organic Microgel Catalysts (Microgelzymes) for Asymmetric Organocatalytic Desymmetrization
dc.contributor.author | Borrmann, Ruediger | |
dc.contributor.author | Palchyk, Volodymyr | |
dc.contributor.author | Pich, Andrij | |
dc.contributor.author | Rueping, Magnus | |
dc.date.accessioned | 2018-08-28T07:48:29Z | |
dc.date.available | 2018-08-28T07:48:29Z | |
dc.date.issued | 2018-08 | |
dc.identifier.citation | Borrmann R, Palchyk V, Pich A, Rueping M (2018) Reversible Switching and Recycling of Adaptable Organic Microgel Catalysts (Microgelzymes) for Asymmetric Organocatalytic Desymmetrization. ACS Catalysis: 7991–7996. Available: http://dx.doi.org/10.1021/acscatal.8b01408. | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.doi | 10.1021/acscatal.8b01408 | |
dc.identifier.uri | http://hdl.handle.net/10754/628294 | |
dc.description.abstract | Adaptable enzyme-mimetic catalysts based on temperature-responsive polymer microgels (microgelzymes) have been developed. By a simple change in the temperature, a microgel catalyst can be reversibly switched into its soluble or precipitated form, thus combining the advantages of homogeneous and heterogeneous catalysis. The responsive microgel reactors show high reactivity and selectivity, as well as good recycling properties in the alcoholysis of cis-tetrahydrophthalic anhydride. | |
dc.description.sponsorship | We thank the BMBF (Project UGR203118812), German Research Foundation (DFG) SFB 985 “Functional Microgels and Microgel Systems” (A.P.), and the Volkswagen Foundation (A.P.) for financial support. | |
dc.publisher | American Chemical Society (ACS) | |
dc.relation.url | https://pubs.acs.org/doi/10.1021/acscatal.8b01408 | |
dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acscatal.8b01408. | |
dc.subject | asymmetric desymmetrization | |
dc.subject | bifunctional sulfonamides | |
dc.subject | cinchona alkaloids | |
dc.subject | switchable colloidal catalyst | |
dc.subject | temperature-responsive microgel | |
dc.title | Reversible Switching and Recycling of Adaptable Organic Microgel Catalysts (Microgelzymes) for Asymmetric Organocatalytic Desymmetrization | |
dc.type | Article | |
dc.contributor.department | KAUST Catalysis Center (KCC) | |
dc.identifier.journal | ACS Catalysis | |
dc.eprint.version | Post-print | |
dc.contributor.institution | Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany | |
dc.contributor.institution | DWI Leibniz Institute for Interactive Materials, Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Forckenberckstr. 50, D-52056 Aachen, Germany | |
kaust.person | Rueping, Magnus | |
refterms.dateFOA | 2018-09-03T06:34:07Z | |
dc.date.published-online | 2018-08 | |
dc.date.published-print | 2018-09-07 |