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dc.contributor.authorSabetghadam, Anahid
dc.contributor.authorLiu, Xinlei
dc.contributor.authorBenzaqui, Marvin
dc.contributor.authorGkaniatsou, Effrosyni
dc.contributor.authorOrsi, Angelica
dc.contributor.authorLozinska, Magdalena M.
dc.contributor.authorSicard, Clemence
dc.contributor.authorJohnson, Timothy
dc.contributor.authorSteunou, Nathalie
dc.contributor.authorWright, Paul A.
dc.contributor.authorSerre, Christian
dc.contributor.authorGascon, Jorge
dc.contributor.authorKapteijn, Freek
dc.date.accessioned2018-06-03T10:38:42Z
dc.date.available2018-06-03T10:38:42Z
dc.date.issued2018-05-14
dc.identifier.citationSabetghadam A, Liu X, Benzaqui M, Gkaniatsou E, Orsi A, et al. (2018) Influence of Filler Pore Structure and Polymer on the Performance of MOF-Based Mixed-Matrix Membranes for CO2 Capture. Chemistry - A European Journal. Available: http://dx.doi.org/10.1002/chem.201800253.
dc.identifier.issn0947-6539
dc.identifier.doi10.1002/chem.201800253
dc.identifier.urihttp://hdl.handle.net/10754/628017
dc.description.abstractTo gain insight into the influence of metal-organic framework (MOF) fillers and polymers on membrane performance, eight different composites were studied by combining four MOFs and two polymers. MOF materials (NH-MIL-53(Al), MIL-69(Al), MIL-96(Al) and ZIF-94) with various chemical functionalities, topologies, and dimensionalities of porosity were employed as fillers, and two typical polymers with different permeability-selectivity properties (6FDA-DAM and Pebax) were selected as matrices. The best-performing MOF-polymer composites were prepared by loading 25wt% of MIL-96(Al) as filler, which improved the permeability and selectivity of 6FDA-DAM to 32 and 10%, while for Pebax they were enhanced to 25 and 18%, respectively. The observed differences in membrane performance in the separation of CO from N are explained on the basis of gas solubility, diffusivity properties, and compatibility between the filler and polymer phases.
dc.description.sponsorshipFinancial support of the European Research Council under theEuropean Union’s Seventh Framework Programme (FP/2007-2013), M4CO2 project (608490) is gratefully acknowledged.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201800253
dc.rightsArchived with thanks to Chemistry - A European Journal
dc.subjectComposite materials
dc.subjectGas separation
dc.subjectMembranes
dc.subjectMetal-organic frameworks
dc.subjectPolymers
dc.titleInfluence of Filler Pore Structure and Polymer on the Performance of MOF-Based Mixed-Matrix Membranes for CO2 Capture
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemistry - A European Journal
dc.eprint.versionPost-print
dc.contributor.institutionCatalysis Engineering-ChemE; Delft University of Technology; Van der Maasweg 9 2629HZ Delft The Netherlands
dc.contributor.institutionInstitut des Matériaux Poreux de Paris, FRE 2000 CNRS, Ecole Normale Supérieure, Ecole Supérieure de Physique et des, Chimie Industrielles de Paris; PSL Research University; 75005 Paris France
dc.contributor.institutionInstitut Lavoisier de Versailles, UMR CNRS 8180; Université de Versailles St Quentin en Yvelines, Université Paris Saclay; 45 av. des Etats-Unis 78035 Versailles France
dc.contributor.institutionEaStCHEM School of Chemistry; University of St Andrews, Purdie Building; North Haugh St Andrews, Fife KY16 9ST UK
dc.contributor.institutionJohnson Matthey Technology Centre; Blount's Court Road, Sonning Common Reading RG4 9NH UK
kaust.personGascon, Jorge
dc.date.published-online2018-05-14
dc.date.published-print2018-06-04


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