Show simple item record

dc.contributor.authorElafandy, Rami T.
dc.contributor.authorElafandy, Rami T.
dc.contributor.authorMin, Jung-Wook
dc.contributor.authorZhao, Chao
dc.contributor.authorNg, Tien Khee
dc.contributor.authorOoi, Boon S.
dc.date.accessioned2018-06-03T08:15:54Z
dc.date.available2018-06-03T08:15:54Z
dc.date.issued2018-05-30
dc.identifier.citationElAfandy RT, Ebaid M, Min J-W, Zhao C, Ng TK, et al. (2018) Flexible InGaN nanowire membranes for enhanced solar water splitting. Optics Express 26: A640. Available: http://dx.doi.org/10.1364/oe.26.00a640.
dc.identifier.issn1094-4087
dc.identifier.doi10.1364/oe.26.00a640
dc.identifier.urihttp://hdl.handle.net/10754/628009
dc.description.abstractIII-Nitride nanowires (NWs) have recently emerged as potential photoelectrodes for efficient solar hydrogen generation. While InGaN NWs epitaxy over silicon is required for high crystalline quality and economic production, it leads to the formation of the notorious silicon nitride insulating interface as well as low electrical conductivity which both impede excess charge carrier dynamics and overall device performance. We tackle this issue by developing, for the first time, a substrate-free InGaN NWs membrane photoanodes, through liftoff and transfer techniques, where excess charge carriers are efficiently extracted from the InGaN NWs through a proper ohmic contact formed with a high electrical conductivity metal stack membrane. As a result, compared to conventional InGaN NWs on silicon, the fabricated free-standing flexible membranes showed a 10-fold increase in the generated photocurrent as well as a 0.8 V cathodic shift in the onset potential. Through electrochemical impedance spectroscopy, accompanied with TEM-based analysis, we further demonstrated the detailed enhancement within excess charge carrier dynamics of the photoanode membranes. This novel configuration in photoelectrodes demonstrates a novel pathway for enhancing the performance of III-nitrides photoelectrodes to accelerate their commercialization for solar water splitting.
dc.description.sponsorshipBSO, TKN and CZ acknowledge funding support from King Abdulaziz City for Science and Technology (KACST) Technology Innovation Center (TIC) for Solid State Lighting, grant no. KACST TIC R2-FP-008. King Abdullah University of Science and Technology (KAUST) baseline funding, grant no. BAS/1/1614-01- 01.
dc.publisherThe Optical Society
dc.relation.urlhttps://www.osapublishing.org/oe/abstract.cfm?uri=oe-26-14-A640
dc.rightsThis paper was published in Optics Express and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: https://doi.org/10.1364/OE.26.00A640 . Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under law.
dc.rights.urihttps://doi.org/10.1364/OA_License_v1
dc.titleFlexible InGaN nanowire membranes for enhanced solar water splitting
dc.typeArticle
dc.contributor.departmentComputer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
dc.contributor.departmentElectrical Engineering Program
dc.contributor.departmentPhotonics Laboratory
dc.identifier.journalOptics Express
dc.eprint.versionPublisher's Version/PDF
kaust.personElafandy, Rami T.
kaust.personElafandy, Rami T.
kaust.personMin, Jung-Wook
kaust.personZhao, Chao
kaust.personNg, Tien Khee
kaust.personOoi, Boon S.
kaust.grant.numberBAS/1/1614-01- 01
refterms.dateFOA2018-06-14T08:25:43Z
dc.date.published-online2018-05-30
dc.date.published-print2018-07-09


Files in this item

Thumbnail
Name:
oe-26-14-A640.pdf
Size:
5.794Mb
Format:
PDF
Description:
Published Version

This item appears in the following Collection(s)

Show simple item record