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dc.contributor.authorNayak, Pranati
dc.contributor.authorJiang, Qiu
dc.contributor.authorMohanraman, Rajeshkumar
dc.contributor.authorAnjum, Dalaver H.
dc.contributor.authorHedhili, Mohamed N.
dc.contributor.authorAlshareef, Husam N.
dc.date.accessioned2018-05-29T11:09:56Z
dc.date.available2018-05-29T11:09:56Z
dc.date.issued2018-05-25
dc.identifier.citationNayak P, Jiang Q, Mohanraman R, Anjum DH, Hedhili MN, et al. (2018) Inherent Electrochemistry and Charge Transfer Properties of Few-Layer Two Dimensional Ti3C2Tx MXene. Nanoscale. Available: http://dx.doi.org/10.1039/c8nr01883a.
dc.identifier.issn2040-3364
dc.identifier.issn2040-3372
dc.identifier.doi10.1039/c8nr01883a
dc.identifier.urihttp://hdl.handle.net/10754/627975
dc.description.abstractWe report the effect of Ti3C2Tx MXene flake thickness on its inherent electrochemistry and heterogeneous charge transfer characteristics. It is shown that the Ti3C2Tx undergoes irreversible oxidation in the positive potential window, which strongly depends on the flake thickness and pH of the electrolyte. Few-layer Ti3C2Tx exhibits faster electron transfer kinetics (k0=0.09533 cm/s) with Fe(CN)64−/3− redox mediator compared to multi-layer Ti3C2Tx (k0= 0.00503 cm/s). In addition, few-layer free standing Ti3C2Tx film electrode remains intact after enduring irreversible oxidation.
dc.description.sponsorshipResearch reported in this publication is supported by funding from King Abdullah University of Science and Technology (KAUST), Saudi Arabia. Authors would like to thank Dr. Narendra Kurra for helpful discussions. Dr. P. Nayak would like to thank DST (Government of India) for the Inspire Faculty Award (Grant No. 04/2015/002660).
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2018/NR/C8NR01883A#!divAbstract
dc.rightsArchived with thanks to Nanoscale
dc.titleInherent Electrochemistry and Charge Transfer Properties of Few-Layer Two Dimensional Ti3C2Tx MXene
dc.typeArticle
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentMaterials Science and Engineering Program
dc.contributor.departmentCore Labs, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia
dc.identifier.journalNanoscale
dc.eprint.versionPost-print
dc.contributor.institutionElectrodics and Electrocatalysis (EEC) Biosensor Division, CSIR- Central Electrochemical Research Institute (CSIR-CECRI), Karaikudi, Tamilnadu, 630006, India
kaust.personJiang, Qiu
kaust.personMohanraman, Rajeshkumar
kaust.personAnjum, Dalaver H.
kaust.personHedhili, Mohamed N.
kaust.personAlshareef, Husam N.


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