Plasmonic Nanowires for Wide Wavelength Range Molecular Sensing

Marinaro, Giovanni; Das, Gobind; Giugni, Andrea; Allione, Marco; Torre, Bruno; Candeloro, Patrizio; Kosel, Jürgen; Di Fabrizio, Enzo M.

Plasmonic Nanowires for Wide Wavelength Range Molecular Sensing

Abstract

In this paper, we propose the use of a standing nanowires array, constituted by plasmonic active gold wires grown on iron disks, and partially immersed in a supporting alumina matrix, for surface-enhanced Raman spectroscopy applications. The galvanic process was used to fabricate nanowires in pores of anodized alumina template, making this device cost-effective. This fabrication method allows for the selection of size, diameter, and spatial arrangement of nanowires. The proposed device, thanks to a detailed design analysis, demonstrates a broadband plasmonic enhancement effect useful for many standard excitation wavelengths in the visible and NIR. The trigonal pores arrangement gives an efficiency weakly dependent on polarization. The devices, tested with 633 and 830 nm laser lines, show a significant Raman enhancement factor, up to around 6 × 10⁴, with respect to the flat gold surface, used as a reference for the measurements of the investigated molecules.

Citation

Marinaro G, Das G, Giugni A, Allione M, Torre B, et al. (2018) Plasmonic Nanowires for Wide Wavelength Range Molecular Sensing. Materials 11: 827. Available: http://dx.doi.org/10.3390/ma11050827.

Acknowledgements

DFT calculations were carried out using the resources of the Supercomputing Laboratory at King Abdullah University of Science & Technology (KAUST) in Thuwal, Saudi Arabia